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Performance improvement of organic bulk heterojunction solar cells by using dihydroxybenzene as additive
  • ISSN号:1673-1905
  • 期刊名称:《光电子快报:英文版》
  • 时间:0
  • 分类:TQ127.11[化学工程—无机化工] TM914.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]Key Laboratory of Display Materials and Photoelectric Devices, Education Ministry of China, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China, [2]Tianjin Key Lab. for Photoelectric Materials and Devices, Tianjin University of Technology, Tianjin 300384, China, [3]Biomolecular and Organic Electronics, Center of Organic Electronics, Department of Physics, Chemistry and Biology (IFM), Linkoping University, Linkoping 58183, Sweden
  • 相关基金:supported by the National Natural Science Foundation of China (Nos.60876046 and 60976048); the Key Project of Chinese Ministry of Education (No.209007); Tianjin Natural Science Council (No.10ZCKFGX01900); the Scientific Developing Foundation of Tianjin Education Commission (No.20100723) and the Tianjin Key Discipline of Material Physics and Chemistry
中文摘要:

我们 poly 基于 regioregular 报导器官的太阳能电池(振荡) 的提高的表演(3-hexylthiophene )(P3HT ) 并且 methanofullerene [6,6 ] 苯基由在活跃的层把 dihydroxybenzene 用作添加剂的 C61 奶油的酸甲基酉旨(PCBM ) 混合。设备的电的特征上的添加剂的内容的效果被学习。有 0.2 wt% dihydroxybenzene 添加剂的设备在 AM 1.5G ( 100 mW/cm2 )的模仿的太阳的照明下面与 12.5 mA/cm2 , 0.65 V 的 V oc ,和66.6%的 FF 的 J sc 完成4.58%的最好的力量变换效率( PCE ),与有3.39%的 PCE 的控制设备相比(35%改进与控制设备相比)。XRD 测量表明添加剂的增加导致 P3HT 的结晶化并且建立好互连网络增加施主和领受人的接触区域,然后帮助收费有效地被转移到电极减少再结合的机会。所有证据显示 dihydroxybenzene 是可能的是能提高器官的体积异质接面太阳能电池的表演的有希望的新类型添加剂。

英文摘要:

We report the enhanced performance of organic solar cells(OSCs) based on regioregular poly(3-hexylthiophene)(P3HT) and methanofullerene [6,6]-phenyl C61-butyric acid methyl ester(PCBM) blend by using dihydroxybenzene as additive in the active layer.The effect of the content of the additives on electrical characteristics of the device is studied.The device with 0.2 wt% dihydroxybenzene additive achieves the best power conversion efficiency(PCE) of 4.58% with Jsc of 12.5 mA/cm2,Voc of 0.65 V,and FF of 66.6% under simulated solar illumination of AM 1.5G(100 mW/cm2),compared with the control device with PCE of 3.39%(35% improvement compared with the control device).The XRD measurement reveals that the addition of additives induces the crystallization of P3HT and establishes good inter-network to increase the contact area of donor and acceptor,and then helps charge to be effectively transferred to the electrode to reduce the chance of recombination.All evidences indicate that the dihydroxybenzene is likely to be a promising new type additive that can enhance the performance of organic bulk heterojunction solar cells.

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期刊信息
  • 《光电子快报:英文版》
  • 主管单位:
  • 主办单位:天津理工大学
  • 主编:巴恩旭
  • 地址:天津市西青区宾水西道391号
  • 邮编:300384
  • 邮箱:Oelett@yahoo.com.cn
  • 电话:022-23679707 23657134
  • 国际标准刊号:ISSN:1673-1905
  • 国内统一刊号:ISSN:12-1370/TN
  • 邮发代号:6-198
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
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  • 被引量:147