合成了联苯型液晶聚氨酯(ICPU),并以其为增韧荆对环氧树脂(EP)进行增韧改性,研究了LCPU含量对LCPU/EP复合材料力学性能的影响。利用X射线衍射、动态粘弹谱仪、扫描电镜等手段对LCPU/EP复合材料的动态热力学性能及断裂面的微观形貌进行了研究。结果表明,LCPU的加入使LCPU/EP复合材料的冲击强度提高2倍~3倍,弯曲强度增加了40%~60%,材料的玻璃化转变温度(Tg)及储能模量(E′g)也有很大程度的提高。
Biphenyl type liquid crystalline polyurethane(LCPU) was synthesized and used as toughening to modify epoxy resin(EP), and the effects of LCPU contents on the mechanical properties of LCPU/EP composites were studied. The fracture surface and the dynamic thermal mechanical properties of LCPU/EP composites were investigated by the X-ray diffraction (XRD) patterns, dynamic mechanical spectrometer and scanning electron microscope. The results show that the impact strength of LCPU/EP composites is increased to 2-3 times than that of pure epoxy resin, flexural strength is increased by 40% -60%. The glassy transition temperature(Tg) and the storage modulus at glassy state (E′g) of composites are improved too.