通过实例就非对称烯烃反应(加卤素、加次卤酸、溶剂汞化-脱汞反应、硼氢化-氧化反应、稀冷高锰酸钾氧化反应、过酸氧化反应等)的区域选择性和立体专一性进行详细分析,并根据反应机理讨论了产物的立体构型.
The regioselectivity and stereospecificity of reaction of asymmetrical alkenes such as addition of halogen, addition of hypohalous acid, oxymercuration-demercuration reaction, hydroboration-oxidation reaction, oxidation by dilute and cold permanganate, oxidation by peracid, etc. are analyzed in detail by examples, and the stereo-configuration of the reaction products are also discussed according to the mechanism.