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以结构为主线结合对比法进行杂环化合物教学
  • ISSN号:1000-8438
  • 期刊名称:大学化学
  • 时间:2014
  • 页码:15-19
  • 分类:TH117[机械工程—机械设计及理论]
  • 作者机构:西北大学化学与材料科学学院合成与天然功能分子化学教育部重点试验室,陕西西安710127
  • 相关基金:西北大学科研启动基金和国家基础人才培养基金项目(J1210057)资助.
  • 相关项目:西北大学化学基地
中文摘要:

采用恒电位测试方法研究了当载荷范围为5~20 N、电位范围为–0.6~0.3 V时镍基合金K4169/氧化铝陶瓷球摩擦副在人工海水中的腐蚀磨损行为,并根据试验数据获得了K4169合金的腐蚀磨损图(总损失图、磨损机理图和交互作用图).结果表明:K4169合金在室温下的人工海水中有良好的耐腐蚀性能,腐蚀速率为0.004 2 mm/a;磨损量Wc为总损失量T值的87.1%~96.8%,表明腐蚀磨损中K4169合金的损失以机械磨损为主,腐蚀损失量Cw很小.以ΔCw/ΔWc为判据可知:协同作用、加和作用和对抗作用均存在于K4169合金在人工海水的腐蚀磨损中.

英文摘要:

In this study, the tribo-corrosion behavior of K4169 nickel-based alloy in sliding against an A1203 ceramic ball in artificial seawater was investigated using an potentiostatic method in applied loads of 5 N to 20 N and potentials from -0.6 V to 0.3 V. And wastage map, wear mechanism map and synergistic map of K4169 alloy were plotted according to the experimental data. The calculated corrosion rate of K4169 alloy was as low as 0.004 2 mm/a, indicating the alloy had good corrosion resistance in artificial seawater at room temperature. According to the wastage map, the total material loss rate ofK4169 alloy was contributed by wear loss because the ratio of wear loss rate to total material loss rate ranged from 87.1% to 96.8%. Corrosion loss had very limited impact on the total material loss. Two wear regimes, i.e. abrasion regime at higher load and abrasion-corrosion at lower load, were observed. Using △Cw/△Wc as the criteria, composite effects, i.e. synergistic effect, additive effect and antagonistic effect, were identified in the tribo-corrosion process.

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期刊信息
  • 《大学化学》
  • 主管单位:中华人民共和国教育部
  • 主办单位:北京大学 中国化学会
  • 主编:段连运
  • 地址:北京大学化学楼C区202
  • 邮编:100871
  • 邮箱:
  • 电话:010-62751721
  • 国际标准刊号:ISSN:1000-8438
  • 国内统一刊号:ISSN:11-1815/O6
  • 邮发代号:82-314
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版)
  • 被引量:9145