利用磁性纳米粒子Fe_3O_4表面的聚多巴胺(PDA)对银离子的吸附作用,采用种子诱导法制备了载银磁性纳米粒子(PDA-Fe_3O_4@Ag)。采用UV-Vis(紫外-可见)光谱对PDA-Fe_3O_4@Ag纳米粒子的制备过程进行了分析,采用FTIR(红外光谱)、XRD(X射线衍射仪)、TEM(透射电镜)和VSM(振动样品磁强计)等手段对所得的PDA-Fe_3O_4@Ag粒子进行表征;研究了PDA-Fe_3O_4@Ag对4-硝基苯酚还原反应的催化作用,还测试了其抗菌性能。结果表明,纳米金种子的存在是制备PDA-Fe_3O_4@Ag纳米粒子的关键;在外加磁场作用下该磁性催化剂可以容易地从反应体系中分离,经多次循环使用后仍具有良好的催化性能;此外PDA-Fe_3O_4@Ag纳米粒子具有杀菌性能,且经磁分离回收循环利用5次后仍呈现对金黄色葡萄球菌较好的杀菌效果。
Silver-deposited magnetic nanoparticles(PDA-Fe_3O_4@Ag) were prepared though the seed-mediated method exploiting the adsorption of silver ions by the polydopamine(PDA) which was coated on the surface of Fe_3O_4.The preparation process was studied using UV-Vis spectra and the prepared nanoparticles were characterized with several analytical techniques including Fourier-transform infrared(FT-IR),X-ray diffraction(XRD),transmission electron microscopy(TEM),and vibrating sample magnetometer(VSM).The catalytic action on the reduction of 4-nitrophenol and the antibacterial property of PDA-Fe_3O_4@Ag were studied.The result indicates that the existence of gold seeds is the key to prepare PDA-Fe_3O_4@Ag nanoparticles.The magnetic catalyst can be separated easily from the reaction system by applied magnetic field,and still has good catalytic performance after repeated recycling.In addition,PDA-Fe_3O_4@Ag nanoparticles exhibit bactericidal properties,and still shows good bactericidal effect on S.aureus after recycling use for 5 times.