中文摘要：

六二度有三齿并且有 1,2,3-triazole-containing ligand 的二 tris 有二齿的 cyclometalated 钌建筑群被准备了并且描绘。建筑群的单个水晶的X光检查分析[( MeOptpy ) Ru ( Budtab )]( PF6 )并且[( Mebip ) Ru ( Budtab )]( PF6 )在 MeOptpy 是 4-p-methoxyphenyl-2,2:6,2-terpyridine 的地方，被介绍， Budtab 是 1,3-di ( N-n-butyl-1,2,3-triazol-4-yl )的 2-deprotonated 形式苯，并且 Mebip 是二度( N-methyl-benzimidazolyl ) pyridine 。这些建筑群的电子性质被分光镜、电气化学的分析探查。时间依赖者密度功能的理论计算被执行了帮助吸收系列的任务。

英文摘要：

Six bis-tridentate and two tris-bidentate cyclometalated ruthenium complexes with a 1,2,3-triazole-containing ligand have been prepared and characterized. Single-crystal X-ray analyses of complexes [（MeOptpy）Ru（Budtab）]-（PF6） and [（Mebip）Ru（Budtab）]（PF6） are presented, where MeOptpy is 4′-p-methoxyphenyl-2,2′：6′,2＂-terpyridine, Budtab is the 2-deprotonated form of 1,3-di（N-n-butyl-l,2,3-triazol-4-yl）benzene, and Mebip is bis（N-methyl-ben-zimidazolyl）pyridine. The electronic properties of these complexes are probed by spectroscopic and electrochemical analyses. Time-dependent density functional theory calculations have been performed to assist the assignment of the absorption spectra.