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Al粉、Si粉对低碳Al2O3-C滑板显微结构和高温力学性能的影响
  • ISSN号:1001-1935
  • 期刊名称:《耐火材料》
  • 时间:0
  • 分类:TQ175.71[化学工程—硅酸盐工业]
  • 作者机构:[1]武汉科技大学耐火材料与高温陶瓷国家重点实验室培育基地,湖北武汉430081
  • 相关基金:国家自然科学基金资助项目(51174152);国家973计划资助项目(2012CB722702);武汉市晨光计划资助项目(201271031379).
中文摘要:

为了改善低碳Al2O3-C滑板的高温力学性能,在质量分数65%的电熔白刚玉颗粒、25%的白刚玉细粉、6%活性α-Al2O3粉、4%的石墨+炭黑、外加4%酚醛树脂的滑板配料中,分别以3%(W)的灿粉或Si粉或3%(w)灿粉+3%(w)Si粉等量替代白刚玉细粉,混匀后在150MPa下压制成140mm×25mm×25mm的试样,经200℃24h干燥,1400℃埋焦炭处理3h后,检测其高温抗折强度和抗热震性,并分析物相组成及显微结构。结果表明:单加舢粉的试样高温抗折强度高于单加Si粉的,但前者热震后残余抗折强度比后者低;与单加Al粉或Si粉的试样相比,同时加灿粉和Si粉的试样具有更高的高温抗折强度和更优的抗热震性。力学性能的变化与试样中原位生成的非氧化物相密切相关:在单加舢粉或Si粉的试样中分别有棒状A1N晶须或纤维状SiC晶须生成;而同时加Al粉和Si粉的试样中除了有AlN晶须和SiC晶须生成外,还原位生成了六角板状的SiAlON相,并相互交织在一起。

英文摘要:

The basic formulation of Al2O3-C slide plates was 65% (in mass,similar hereinafter) white fused corun- dum particles,25% white fused corundum fines,6% active α-Al2O3 powder,4% carbon black and flake graphite, and additional 4% phenolic resin. Based on this formulation,3% AI powder,3% Si powder,and 3% AI + 3% Si powder were used to substitute equivalent white corundum fines to improve the hot mechanical properties of Al2O3-C slide plates. The specimens with size of 140 mm ×25 mm ×25 mm were pressed at 150 MPa,dried at 200 ℃ for 24 h,and hot treated at 1 400 ℃ for 3 h in carbon embedded condition. Then hot modulus of rupture and thermal shock resistance of the specimens were tested and the phase compositions and microstructure were an- alyzed. The results show that specimen with 3% AI powders has higher hot modulus of rupture but lower residual modulus of rupture after thermal shock than the specimen with 3% Si powder;the specimen with 3% AI and 3% Si powder exhibits both higher hot modulus of rupture and better thermal shock resistance compared with the specimens with only AI or Si powders; the change of mechanical property is closely related with the in-situ formed nonoxides.AIN in the form of bars is formed in specimens with AI powder;fibrous SiC whiskers are formed in specimens with Si powder;in the specimens with both AI and Si powders,besides AIN and SiC whisk- ers,hexagonal tabular SiAION is in-situ synthesized which interlocks with each other.

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期刊信息
  • 《耐火材料》
  • 北大核心期刊(2011版)
  • 主管单位:中钢集团洛阳耐火材料研究院有限公司
  • 主办单位:中钢集团洛阳耐火材料研究院有限公司
  • 主编:柴俊兰
  • 地址:河南省洛阳市西苑路43号
  • 邮编:471039
  • 邮箱:nhcl@nhcl.com.cn
  • 电话:0379-64205960 64205958
  • 国际标准刊号:ISSN:1001-1935
  • 国内统一刊号:ISSN:41-1136/TF
  • 邮发代号:36-19
  • 获奖情况:
  • 河南省优秀期刊一等奖或二等奖,中国冶金优秀期刊二等奖,2008、2010、2013年连续次被评为“河南省自然科学...
  • 国内外数据库收录:
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  • 被引量:4459