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离子探针锆石U-Pb定年的“高U效应”
  • ISSN号:1007-2802
  • 期刊名称:《矿物岩石地球化学通报》
  • 时间:0
  • 分类:P597[天文地球—地球化学;天文地球—地质学]
  • 作者机构:中国科学院地质与地球物理研究所,岩石圈演化国家重点实验室,北京100029
  • 相关基金:国家自然科学基金项目(41521062,41222023)
作者: 李秋立
中文摘要:

高U锆石的离子探针U-Pb分析中存在随U含量升高而表现更老的现象,称之为"高U效应"。本文尝试性总结了UPb衰变过程可造成锆石晶格的损伤、后期热愈合作用造成损伤锆石的结构变化、离子探针Pb/U离子化效率差异等因素,认为"高U效应"主要源于损伤锆石处于微尺度的混晶状态(晶态Zr SiO_4、ZrO_2和无定形SiO_2),放射成因Pb容易进入无定性SiO_2,而U进入ZrO_2,造成Pb/U离子化效率差与锆石情况不同。统计发现,高U锆石不仅表现为偏老的"高U效应",还受损伤导致Pb丢失的影响,结果存在较大不确定性,不适宜离子探针精确U-Pb定年,应在测试选点过程中避免,或选用其他矿物,如独居石、磷钇矿、榍石等代替。

英文摘要:

"High-U effect"is used to describe a phenomenon during SIMS zircon U-Pb dating that the apparent Pb / U ages of high-U zircons show positive correlation with their high U contents. In this paper,based on reviewing many investigations on radiogenic damage effect on the lattice of zircons by the U-Pb decay,and the structural change of damaged zircon caused by the thermal annealing effect,and the efficiency differences between Pb and U ionization of zircons by using SIMS,it is believed that the ″High-U effect″ could be mainly caused by the mixture state of crystalline crystals of Zr SiO_4,ZrO_2 and amorphous state of SiO_2 for the radiogenic damaged zircons,as the radiogenic Pb is in favor to combine with the amorphous SiO_2,while the U is in favor to enter into the lattice of ZrO_2,resulting in the efficiency differences between Pb and U ionization during SIMS analysis. In addition,based on the statistics,the high-U zircon not only has "High-U effect",but also Pb-depletion effect due to the radiogenic damage,resulting in the relatively big uncertainties for the U-Pb dating results. Therefore,it is believed that the high-U zircon is not suitable and should be avoided for precise SIMS U-Pb dating. It is recommended that some other minerals,such as monazite,xenotime,and titanite,could be good substitutes of the high U zircon for SIMS U-Pb dating.

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期刊信息
  • 《矿物岩石地球化学通报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学技术协会
  • 主办单位:中国矿物岩石地球化学学会 中国科学院地球化学研究所
  • 主编:
  • 地址:贵阳市观山湖区林城西路99号
  • 邮编:550081
  • 邮箱:kydhtb@vip.skleg.cn
  • 电话:0851-85895823 85893143
  • 国际标准刊号:ISSN:1007-2802
  • 国内统一刊号:ISSN:52-1102/P
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰地学数据库,荷兰文摘与引文数据库,美国地质文献预评数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:8813