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Characterization of the cooling process of solid n-alkanes via terahertz spectroscopy
  • ISSN号:1009-7104
  • 期刊名称:《物理与工程》
  • 时间:0
  • 分类:TN[电子电信]
  • 作者机构:Beijing Key Laboratory of Optical Detection Technology for Oil and Gas, China University of Petroleum, Beijing 102249, China
  • 相关基金:This work was supported by the National Basic Research Program of China (No. 2014CB744302), the Specially Funded Program on National Key Scientific Instruments and Equipment Develop- ment (No. 2012YQ140005), the China Petroleum and Chemical Industry Association Science and Technology Guidance Program (No. 20160107), and the National Natural Science Foundation of China (Grant No. 11574401).
中文摘要:

兆兆赫(THz ) 时间域光谱学技术被用来描绘稳固的 n 链烷的冷却过程。n-octadecane, n-nonadecane, n-eicosane, n-heneicosane, n-docosane,和 n-pentacosane 的 THz 波形用上述的 noncontact 与冷却时间被获得光方法。THz 信号的山峰值被发现与 n 链烷的冷却温度有关。THz 波浪对在液体的粒子的尺寸和结构敏感;因此, n 链烷的结晶化过程被监视。一个实验方程基于信号变细被建议到份量上在样品区分结构的顺序的内容变化。结果介绍新 noncontact 为经由 THz 时间域描绘蜡结晶化的光途径光谱学。

英文摘要:

The terahertz (THz) time-domain spectroscopy technique was used to characterize the cooling process of solid n-alkanes. The THz waveforms of n-octadecane, n- nonadecane, n-eicosane, n-heneicosane, n-docosane, and n-pentacosane were obtained with the cooling time using the aforementioned noncontact optical method. The peak values of the THz signal were found to be related to the cooling temperature of n-alkanes. The THz wave was sensitive to the size and structure of particles in the liquid; therefore, the crystallization process of n-alkanes was monitored. An empirical equation based on signal attenuation was proposed to quantitatively distinguish the content change of structural order in the samples. Results present a new noncontact optical approach for characteriz- ing wax crystallization via THz time-domain spectroscopy.

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期刊信息
  • 《物理与工程》
  • 中国科技核心期刊
  • 主管单位:国家教育部
  • 主办单位:清华大学
  • 主编:顾牡
  • 地址:清华大学学研大厦B座6层
  • 邮编:100084
  • 邮箱:physAEng@tup.tsinghua.edu.cn
  • 电话:010-62788108-812
  • 国际标准刊号:ISSN:1009-7104
  • 国内统一刊号:ISSN:11-4483/O3
  • 邮发代号:82-250
  • 获奖情况:
  • 国内外数据库收录:
  • 中国中国科技核心期刊
  • 被引量:3771