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奇球菌(Deinococcus radiodurans)吸附U(Ⅵ)的试验研究
  • ISSN号:1009-6094
  • 期刊名称:安全与环境学报
  • 时间:0
  • 页码:23-26
  • 语言:中文
  • 分类:X703.1[环境科学与工程—环境工程]
  • 作者机构:[1]南华大学污染控制与资源化技术湖南省重点实验室,湖南衡阳421001, [2]南华大学铀矿冶生物技术国防重点学科实验室,湖南衡阳421001
  • 相关基金:国家自然科学基金项目(10775065,20707008)
  • 相关项目:耐辐射、超富集铀基因工程菌的构建与应用基础研究
中文摘要:

为了探讨奇球菌对铀的吸附特性,研究了pH值、吸附时间、菌体浓度、铀起始浓度和预处理奇球菌对铀吸附的影响,并考察了菌体上铀的解吸作用。结果表明,在pH值为4.0时,吸附量最大;30 min吸附基本达到平衡;吸附量与菌体浓度负相关,与铀起始浓度正相关,吸附量最大可达126.27 mg/g。经乙醇预处理的菌体,其吸附量有所上升。解吸试验表明,0.5 mol/LNa2CO3对铀的解吸率可达93.15%。与Langmuir吸附模型相比,奇球菌对U(Ⅵ)的吸附更符合Freundlich吸附等温式。

英文摘要:

The present paper is to introduce our study of the biosorption of uranium by Deinococcus radiodurans, the effect of pH, contact time, the initial U ( Ⅵ ) concentration, the concentration of D. radiodurans, as well as the various pretreatment procedures on the biosorption in addition to the desorption efficiency were studied. The results of our research have shown that the maximal adsorption quantity can reach 48.62 mg/g with the optimal pH value being 4.0.The absorption rate can be expected to reach 95.12% when the absorption gets balanced in about 30 min. And, then, it would turn to be a dynamic adsorption-desorption process. The adsorption quantity proves in negative correlation with the concentration of D. radiodurans when the adsorption rate reaches 95.13% at 5 mg/L of the cell biomass of D. radiodarans. On the other hand, the adsorption quantity can also be expected to be positively correlated with the concentration of U( Ⅵ ), with its highest degree being over 126.27 mg/g. The results of different pretreatments indicate that the adsorption degree with ethanol pretreated biomass can be higher beyond the control level, if the adsorption quantity can increase from 46.66 mg/g to 47.74 mg/g. Meanwhile, the desorption of U(Ⅵ) from D. radiodurans cells can be very high in Na2CO3 and NaHCO3 solution, the desorption rate of 0.5 mol/L Na2CO3 solution reached 93.15% . In addition, the adsorption isotherm of U(Ⅵ) on D. radiodurans can be in good agreement with Freundlich equation (correlation coefficient = 0.999 4), that is, better than with Langmuir equation. Therefore, the absorption process is by nature not merely a single molecular change on the surface adsorption.

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期刊信息
  • 《安全与环境学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国兵器工业集团公司
  • 主办单位:北京理工大学 中国环境科学学会 中国职业安全健康协会
  • 主编:冯长根
  • 地址:北京市海淀区中关村南大街5号
  • 邮编:100081
  • 邮箱:aqyhjxb@263.net;aqyhjxb@wuma.com.cn
  • 电话:010-68913997
  • 国际标准刊号:ISSN:1009-6094
  • 国内统一刊号:ISSN:11-4537/X
  • 邮发代号:2-770
  • 获奖情况:
  • 获首届《CAJ-CD》执行优秀期刊奖,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:17182