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中文摘要：
研究了Tb3＋自敏化效应与Gd3＋-Tb3＋能量转移对硅酸盐玻璃发光性能的影响。结果表明，随着Tb3＋掺杂量的增加，Tb3＋的400—450nm蓝色荧光发射减弱，而485nm和545nm绿光发射增强。Tb3＋掺杂硅酸盐玻璃中，Tb3＋之间存在能量转移，产生自敏化效应，这种转移是由Tb3＋之间电偶极-电四极的相互作用引起的共振能量转移。Gd3＋通过Gd3＋-Tb3＋间的能量转移对Tb3＋的发光起敏化作用，这种能量转移主要是偶极与偶极相互作用引起的共振转移。
英文摘要：
The effect of Tb3＋ self- sensitization and Gd3 ＋ -Tb3 ＋ energy transfer on luminescent properties of Tb3＋ doped silicate glasses was investigated. Results showed that the intensity of blue emission decreases, but the intensity of green emission increases with increasing of Tb3 ＋ concentration. Tb3 ＋ self - sensitization takes place by the energy transfer in the manner of resonance between Tb3 ＋ in silicate glasses , which is caused by the interaction between electric dipole and electric quadrupole C,d3＋ can enhance manner from Gd3 ＋ the luminescence of Tb3＋ in silicate glasses to Tb3 ＋ emission center due to the interaction by the energy transfer in resonance between electric dipoles.
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