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高功率超级电容器用介孔炭电极材料
  • 期刊名称:电化学
  • 时间:0
  • 页码:9-12
  • 语言:中文
  • 分类:TM152[电气工程—电工理论与新技术]
  • 作者机构:[1]防化研究院,北京100083, [2]北京理工大学化工与环境学院,北京100081
  • 相关基金:国家863计划项目(2006AA11A165,2006AA032342),国家自然科学基金(50802112,20633040)资助
  • 相关项目:富氮电容炭的制备与储能机制研究
中文摘要:

以纳米CaCO,为模板、蔗糖为前躯体制备超级电容器用介孔炭电极材料.材料的结构由氮吸附、TEM表征,借助恒流充放电、循环伏安和交流阻抗评价了其在6mol·L^-1KOH电解液中的电化学电容性能.结果表明,蔗糖基介孔炭的比表面积606m^2/g,富含10~30nm的介孔.恒流放电法测得介孔炭在电流密度50mA/g下的比电容为125F/g,大电流倍率性能特别突出.电流密度增大到20000mA/g,比电容还保持有88F/g,远高于进121电容炭,该介孔炭是一种很有前景的高功率超级电容器炭电极材料.

英文摘要:

Mesoporous carbon for supercapacitors was prepared from sucrose using nano-CaCO3 as template. The microstructure of the carbon was characterized with N2 adsorption and transmission electron microscopy (TEM) observation. The electrochemical performances were evaluated in 6mol · L^-1 KOH aqueous electrolyte with galvanostatic charge/discharge, cyclic, vohammetry, and ac impedance spectroscopy. The sucrose-based mesoporous carbon had a surface area of 606 m^2/g and enriched mesopores in the range of 10 - 30 nm. The mesoporous carbon presented a specific capacitance of 125 F/g at a current density of 50 mA/g and outstanding excellent rate performance. As the current density increased to 20 000 mA/g, its capacitance remained at 88 F/g, much higher than the commercial capacitive carbon, indicating that the mesoporous carbon is a promising electrode material for high power supercapacitors.

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