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土壤中常见黏土矿物定量方法的改进研究
  • ISSN号:0564-3945
  • 期刊名称:《土壤通报》
  • 时间:0
  • 分类:S152.1[农业科学—土壤学;农业科学—农业基础科学]
  • 作者机构:[1]南京农业大学资源与环境科学学院,江苏南京210095
  • 相关基金:国家自然科学基金项目(40573057;40971138)资助
中文摘要:

以矿物的X-射线衍射为理论依据,以高岭石、蒙脱石和伊利石作为土壤中黏土矿物的代表,在强度比例因子法的基础上对黏土矿物的定量方法进行了改进研究。实验过程是:将3种矿物按不同比例配制成混合样,利用X-射线衍射仪对各混合样进行测试,根据已知比例计算各种矿物的权重系数,最终确定定量计算的公式:k%=Ik(Ik+1.1881Im+0.9966Ii)×100%、m%=Im/(Im+0.8271Ik+0.5898Ii)×100%、i%=Ii/(Ii+1.1779Ik+2.0676Im)×100%。检验性实验结果表明:所建立的公式不仅操作简便,而且误差较小,高岭石、蒙脱石和伊利石分别为5.9%、6.5%和4.6%。高岭石、蒙脱石和伊利石的实测值与真实值之间的相关性很好,相关系数分别为0.88、0.85和0.92。

英文摘要:

For the quantitative analysis of the minerals in the main clay, namely kaolinite, montmorillonite and illite, on the basis of Gorbunov's Method, an improvement study using X-ray diffraction was done. Experimental processes were as follows. Three minerals with various proportions were mixed. The mixed samples were analyzed with XRD, and the quantitative constants were calculated according to the known proportions. Finally, we determined the quantitative formula as k% = Ik / (Ik + 2.1995Im + 1.0028Ii) × 100%, m% = Im / (Im + 0.6408Ik + 0.5580Ii) × 100% and i% = Ii / (Ii + 1.1731Ik + 2.1594Im) × 100%, respectively. Test research showed that the established formula method was simple with minimum error. The percentage of the Main Clay Minerals, kaolinite, montmorillonite and illite were 5.9%, 6.5% and 4.6% respectively. Quantitative results were highly correlated with true content, the correlation coefficients were 0.88, 0.85 and 0.92, respectively. The established quantitative method was also applicable for other clay mineral combinations.

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期刊信息
  • 《土壤通报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国土壤学会
  • 主编:张玉龙
  • 地址:沈阳市东陵路120号
  • 邮编:110866
  • 邮箱:trtb@periodicals.net.cn
  • 电话:
  • 国际标准刊号:ISSN:0564-3945
  • 国内统一刊号:ISSN:21-1172/S
  • 邮发代号:8-15
  • 获奖情况:
  • 辽宁省优胜期刊,中国土壤学会土壤通报编委会先进集体
  • 国内外数据库收录:
  • 美国化学文摘(网络版),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:32491