中文摘要：

基于联萘衍生物手性构型高度稳定的特点，以光学活性的（R）-2，2＇-二乙炔基-1，1＇-联萘为模板，设计了3个有趣的拓扑环芳分子——含有4个手性联萘单元的（R，R，R）-2a-2c，并探讨了它们的合成。合成路线涉及三甲基硅（Me3Si-）保护基的控制导入，对位取代的芳基连接桥的链接，保护基的脱去以及分子间偶合成环4个步骤．用比旋光度（[a]D），MS，IR，UV-Vis，^1H和^13C NMR以及元素分析表征了这些化合物．

英文摘要：

（R）-2,2＇-Diethynyl-1,1＇-binaphthyl with a highly stable chiral configuration was employed as a structural template, and three novel topologically interesting tetrabinaphthyl cyclophanes （R,R,R,R）-2a-2c were synthesized in an enantiopure form via four-step reactions including the introduction of protecting group （Me3Si-）, linking of para-substituted benzene-bridge, removal of protecting group and intermolecular cross-coupling. The specific rotations （[a]D）, MS, IR, UV-Vis, ^1H and ^13C NMR as well as elemental analysis characterized all intermediates and the target compound 2.