东篱科研大数据发现系统（DRDS）

位置：成果数据库 > 期刊 > 期刊详情页

一类基于苝酰亚胺和亚苯基亚乙炔基交替共轭聚合物的合成与表征

ISSN号：1000-3304
期刊名称：《高分子学报》
时间：0
分类：O631.24[理学—高分子化学;理学—化学] TQ225.262[化学工程—有机化工]
作者机构：[1]复旦大学信息科学与工程学院光科学与工程系先进光子学材料与器件国家重点实验室,上海200433, [2]南京邮电大学信息材料与纳米技术研究院,南京210003
相关基金：国家自然科学基金（基金号60578039,90406021）资助项目;

作者：王瑞杰[1], 浦侃裔[1], 覃春杨[1], 彭波[1], 黄维[2], 韦玮[1]

关键词：苝酰亚胺, 低聚亚苯基亚乙炔基, 电荷分离, 循环伏安, Perylene bisimide, Oligo（p-phenylene ethynylene）, Charge separate state, Electrochemical property

中文摘要：

以1,7“bay”位置溴化苝酰亚胺为电子受体、低聚亚苯基亚乙炔基（OPE）为电子给体,通过Sonagashira反应制备了一系列不同OPE含量的具有p-n结构主链全共轭交替聚合物,并对其光物理和电化学性质进行了表征.紫外-可见吸收光谱表明,聚合物具有较宽的光吸收范围（350~900 nm）,有利于提高体系的光吸收效率;荧光光谱实验发现,对苝酰亚胺单元进行选择性激发,产生由分子内电荷分离所导致的荧光猝灭现象,为该材料应用于光伏器件提供了理论和实验依据.

英文摘要：

Three conjugated copolymers containing different length of oligo （p-phenylene ethynylene ） moieties （OPE） connecting at the bay position of N, N＇-dioctylperylene-3,4：9, 10-tetracarboxylie acid bisimide were designed and synthesized. The three OPE monomers were prepared according to a stepwise synthesis method. This method involves two sets of reaction conditions：desilylation and Pd/Cu-catalyzed coupling. In every two steps,2,5- dihexyloxy-4-[ （trimethylsilyl）ethynyl ] iodobenzene was coupled with the diethynyl compounds which were desilylated from the di（ trimethylsilyl）-ethynyl compounds. Through this approach, undesired oligomerization was avoided and OPE monomer, trimer, pentamer were readily prepared in high purity. The hromination of perylene bisanhydride was carried out under reaction condition with a more than two-fold of bromine in 98 % sulfuric acid. After imidization by n-octylamine with acetic acid as catalyst in NMP, the resultant compound was soluble in dichloromethane, which facilitated its purification. The coupling polymerization was performed by a standard Sonagashira reaction between the acetylene-terminated OPE monomers and perylene monomer, leading to the final three alternative copolymers （P1, P2, P3） .After polymerization reaction has been finished, all polymers dissolved in chloroform and then reprecipitated in methanol for three times, followed by Soxhlet extraction with acetone for 48 h to remove residual catalyst and monomers. The structures of the three polymers were characterized by IR, Elementary analysis and GPC. P1 has limited solubility in common solvents such as THF, diehloromethane, toluene, etc, due to the high rigidity of the backbone as well as the high content of perylene. But the solubility of P2 and P3 was improved dramatically. The photophysical characteristics of the polymers were investigated by UV-Vis and PL spectra in solution. In UV-Vis, the absorptions of perylene in polymers show a large red-shift （nearly 170 nm） compared to that of the