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Sonochemical Synthesis of Two Dimensional C3N4 Nanosheets Supported Palladium Composites and Their Electrocatalytic Activity for Oxygen Reduction and Methanol Oxidation Reaction
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:TQ426.81[化学工程] O643.36[理学—物理化学;理学—化学]
  • 作者机构:State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, Jiangsu 210093, China
  • 相关基金:We greatly appreciate the support of the National Natural Science Foundation of China (Nos. 21475057, 21335004,) and the Program B tbr Outstanding PhD Candidates of Nanjing University. This work was also supported by the Program for New Century Excellent Talents in University (No. NCET-12-0256).
中文摘要:

有为燃料房间的好耐久性和低费用的高度活跃的 electrocatalysts 的准备是高度合乎需要的,但是仍然是重要挑战。这里,我们综合了二维(2D ) C 3 N 4 nanosheets 支持了钯 composites (C 3 经由一条简单、方便的 sonochemical 途径的 N 4/Pd) 。我们系统地学习了同样准备的催化剂的 electrocatalytic 表演。我们发现准备 C 3 N 4/Pd composites 在碱的媒介为氧减小反应(ORR ) 拥有了优秀催化活动和稳定性。鼓励地, C 3 N 4/Pd 催化剂在碱的媒介为甲醇氧化反应(粗腐殖质) 展出优秀 electrocatalytic 活动,比商业 Pt/C 催化剂的甚至好。2D C 3 N 4 nanosheets 与大表面区域和钯 nanoparticles 的优秀分散从他们在 ultrathin 底层材料之间的协同作用效果支持了钯 composites 催化剂结果。这研究证明那个 sonochemical 方法为燃料房间为 electrocatalysts 的准备开创一条新大街。我们期望这些材料是可能的发现例如,在大量应用的使用造成房间,太阳能电池,电池和另外的电气化学的分析。

英文摘要:

The preparation of highly active electrocatalysts with good durability and low cost for fuel cells is highly desir- able but still remains a significant challenge. Here we synthesized two dimensional (2D) C3N4 nanosheets supported palladium composites (C3N4/Pd) via a simple and convenient sonochemical approach. We have systematically stud- ied the electrocatalytic performance of as-prepared catalysts. We found that the prepared C3N4/Pd composites pos- sessed excellent catalytic activity and stability for oxygen reduction reaction (ORR) in alkaline media. Encourag- ingly, the C3N4/Pd catalysts exhibit the excellent electrocatalytic activity for methanol oxidation reaction (MOR) in alkaline media, even better than that of the commercial Pt/C catalyst, The excellent electrocatalytic performance of the 2D C3N4 nanosheets supported palladium composites catalysts results from their synergy effect between the ul- trathin substrate material with large surface area and excellent dispersion of palladium nanoparticles. This study demonstrates that sonochemical method opens up a new avenue for the preparation of electrocatalysts for fuel cells. We expect these materials are likely to find uses in a broad range of applications, for example, fuel cells, solar cells, batteries and other electrochemical analysis.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175