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稀土Pr对有色金属电积用Pb基阳极性能的影响
  • ISSN号:0258-7076
  • 期刊名称:稀有金属
  • 时间:2014.5
  • 页码:720-726
  • 分类:TF813[冶金工程—有色金属冶金]
  • 作者机构:[1]江西理工大学应用科学学院矿冶工程系,江西赣州341000, [2]紫金矿业集团股份有限公司,福建上杭364200
  • 相关基金:国家自然科学基金项目(51364016,51164011)资助
  • 相关项目:用于氨性体系电积锌的新型添加剂合成及其对电极反应机理的影响
中文摘要:

采用二步重熔法制备了不同Pr含量的Pb-Pr合金阳极材料,通过材料力学性能测试、阳极腐蚀测试研究了稀土元素Pr对Pb-Pr合金阳极抗拉强度、耐腐蚀性的影响,并利用循环伏安曲线(CV)和线性极化曲线研究了Pr对Pb-Pr合金阳极电化学行为的影响。研究结果表明:合金抗拉强度随Pr含量增大而增大,当合金中Pr含量达到2.0%(质量分数)时,合金抗拉强度为21.1 MPa,较纯Pb抗拉强度提高了85.1%;稀土元素Pr添加量在1.0%以下时不会对铅基阳极腐蚀性能产生明显影响,当Pr添加量超过1.0%时,Pr的添加使得恒流极化时阳极生成的Pb O2膜层疏松、多孔,降低了铅基合金的耐腐蚀性,当合金中Pr含量达到2.0%时,腐蚀速率提高到13.78 g·cm-2·h-1,较纯Pb(13.10g·cm-2·h-1)提高了5.19%;稀土元素Pr能降低合金电极稳定电位,且电位值随稀土元素含量的增加而减小,Pr含量达到2.0%时,阳极稳定电位约为2.190 V,与纯铅阳极稳定电位(2.314 V)相比下降5.4%。

英文摘要:

Pb-Pr anode alloys with different contents of rare earth element Pr were prepared with two-stage remelting method. The effects of Pr in Pb-Pr anode on tensile strength and corrosion resistance were investigated by measurement of mechanical properties and corrosive tests. The electrochemical behavior of alloy anode was also discussed based on cyclic voltammetry( CV) curves and linear polarization curves. The results showed that tensile strength increased with Pr content increasing. When Pr content was 2. 0%( mass fraction),the tensile strength reached 21. 1 MPa,which was 85. 1% higher than that of pure Pb anode. When Pr content was below1. 0%,it had no obvious influence on the corrosion resistance. Pr addition of more than 1. 0% caused the formation of loose and porous Pb O2 layer during constant current polarization,which reduced the corrosion resistance of lead-based alloys. When Pr content was2. 0%,corrosion rate reached 13. 78 g·cm- 2·h- 1,which was 5.19% higher compared with that of pure Pb anode( 13. 10 g·cm- 2·h- 1). It could also reduce the anode stable potential,and the potential value decreased with rare earth metal content increasing. When Pr content was 2. 0%,the anode stable potential was about 2. 190 V,which decreased by 5. 4% compared with that of pure Pb anode( 2. 314 V).

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期刊信息
  • 《稀有金属》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京有色金属研究总院
  • 主编:屠海令
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:xxsf@grinm.com
  • 电话:010-82241917 62014832
  • 国际标准刊号:ISSN:0258-7076
  • 国内统一刊号:ISSN:11-2111/TF
  • 邮发代号:82-167
  • 获奖情况:
  • 中文核心期刊,冶金工业类核心期刊,中国科技论文统计源期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:13688