排列得好的无限制的多围的碳 nanotube (MWCNT ) 数组经由化学蒸汽免职(CVD ) 被准备在多孔的阳极的铝氧化物(AAO ) 的方法没有是扔任何转变金属的模板催化剂。CVD 温度和热处理的效果详细被学习。排列得好的无限制的 MWCNT 数组超过 600 在 CVD 温度被获得 ? 湡 ?? ′票牤杯湥戠湯 ? 潣灭敬數 ? 潦浲摥眠瑩 ? 数 ? ㈠ ? ‰礠敬敮搠慩桮摹楲敤愠摮瀠特摩湩 ?敤楲慶楴敶 s
Well-aligned open-ended multi-walled carbon nanotube (MWCNT) arrays were prepared via chemical vapor deposition (CVD) method in porous anodic aluminum oxide (AAO) templates without depositing any transition metals as catalyst. Effects of the CVD temperature and heat treatment were studied in detail. Well-aligned open-ended MWCNT arrays were obtained at the CVD temperature above 600℃; when CVD temperature is reduced to around 550℃, CNTs, CNFs and other structures existed at the same time; no CNTs or carbon nanofibres (CNFs) could be fouad as the CVD temperature is below 500℃, and only amorphous carbon in the porous AAO template was found. Experimental results showed that the AAO template is catalytic during the CVD process, and it has the following two effects: to catalyze thermal decomposition of acetylene and to catalyze conversion of carbon decomposed from acetylene into CNTs or CNFs. Heat treatment could improve the graphitization degree, but it might also introduce new defects.