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Preparation of Well-aligned CNT Arrays Catalyzed with Porous Anodic Aluminum Oxide Template
  • ISSN号:1674-0068
  • 期刊名称:《化学物理学报》
  • 时间:0
  • 分类:O613.71[理学—无机化学;理学—化学] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]Hefei Institute of Intelligent Machines, Chinese Academy of Sciences, Hefei 230031, China
  • 相关基金:This project was supported by the National High Technology Research and Development Program of China (863 Program, No. 2004AA302030) and Na- tional Natural Science Foundation of China (NSFC No. 60574095). Tests and analysis are supported by the United Foundation for Testing &: Analysis in Hefei, Chi- nese Academy of Sciences.
中文摘要:

排列得好的无限制的多围的碳 nanotube (MWCNT ) 数组经由化学蒸汽免职(CVD ) 被准备在多孔的阳极的铝氧化物(AAO ) 的方法没有是扔任何转变金属的模板催化剂。CVD 温度和热处理的效果详细被学习。排列得好的无限制的 MWCNT 数组超过 600 在 CVD 温度被获得 ? 湡 ?? ′票牤杯湥戠湯 ? 潣灭敬數 ? 潦浲摥眠瑩 ? 数 ? ㈠ ? ‰礠敬敮搠慩桮摹楲敤愠摮瀠特摩湩 ?敤楲慶楴敶 s

英文摘要:

Well-aligned open-ended multi-walled carbon nanotube (MWCNT) arrays were prepared via chemical vapor deposition (CVD) method in porous anodic aluminum oxide (AAO) templates without depositing any transition metals as catalyst. Effects of the CVD temperature and heat treatment were studied in detail. Well-aligned open-ended MWCNT arrays were obtained at the CVD temperature above 600℃; when CVD temperature is reduced to around 550℃, CNTs, CNFs and other structures existed at the same time; no CNTs or carbon nanofibres (CNFs) could be fouad as the CVD temperature is below 500℃, and only amorphous carbon in the porous AAO template was found. Experimental results showed that the AAO template is catalytic during the CVD process, and it has the following two effects: to catalyze thermal decomposition of acetylene and to catalyze conversion of carbon decomposed from acetylene into CNTs or CNFs. Heat treatment could improve the graphitization degree, but it might also introduce new defects.

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期刊信息
  • 《化学物理学报》
  • 中国科技核心期刊
  • 主管单位:中国科协
  • 主办单位:中国物理学会
  • 主编:杨学明
  • 地址:合肥中国科学技术大学
  • 邮编:230026
  • 邮箱:cjcp@ustc.edu.cn
  • 电话:0551-3601122
  • 国际标准刊号:ISSN:1674-0068
  • 国内统一刊号:ISSN:34-1295/O6
  • 邮发代号:26-62
  • 获奖情况:
  • 1998年获安徽省优秀科技期刊一等奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:4282