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中文摘要：
全氟烷基化反应,特别是三氟甲基化反应一直是有机化学领域的研究热点.近几年来,可见光促进的光氧化还原催化的有机化学反应,因其本身所固有的条件温和、绿色和环保等优点而倍受合成化学家的青睐.该方法学也被成功地应用于一系列三氟甲基化反应.本文主要按照三氟甲基源分类,总结了近年来可见光促进的光氧化还原催化的三氟甲基化反应的研究进展,并对其发展趋势进行了展望.
英文摘要：
Perfluoroalkylation,especially trifluoromethylation has long been a hot research area in synthetic organic chemistry.In addition,visible light photoredox catalytic organic transformations have attracted great attention due to their inherent green feature.Recently,visible light photoredox catalysis has been successfully applied to a series of trifluoromethylation reactions.In this review,we will highlight the recent advancement in this field and organize the review article according to trifluoromethyl sources.
同期刊论文项目
同项目期刊论文
Enantioselective Conjugate Addition of Oximes to Trisubstituted beta-Nitroacrylates: An Organocataly
[4+3] Cycloaddition of in-situ generated azoalkenes with C,N-cyclic azomethine imines: Efficient syn
Construction of Optically Active Indolines by Formal [4+1] Annulation of Sulfur Ylides and N-(ortho-
Enantioselective synthesis of dihydropyrazoles by formal [4+1] cycloaddition of in situ-derived azoa
An efficient synthesis of enol phosphates via organic base-promoted addition of phosphites to 4-oxo-
Design of chiral sulfoxide-Schiff base hybrids and their application in Cu-catalyzed asymmetric Henr
Facile Synthesis of Enantioenriched C-gamma-Tetrasubstituted alpha-Amino Acid Derivatives via an Asy
Asymmetric Cyclopropanation of beta,gamma-Unsaturated alpha-Ketoesters with Stabilized Sulfur Ylides
Highly Efficient Aerobic Oxidative Hydroxylation of Arylboronic Acids: Photoredox Catalysis Using Vi
Visible-Light-Induced Oxidation/[3+2] Cycloaddition/Oxidative Aromatization Sequence: A Photocatalyt
Highly Enantioselective Organocatalytic Michael Addition/Cyclization Cascade Reaction of Ylideneoxin
Visible Light-Induced Aerobic Oxyamidation of Indoles: A Photocatalytic Strategy for the Preparation
Dual Activation in Organocatalysis: Design of Tunable and Bifunctional Organocatalysts and Their App
Hydrogen-Bond-Mediated Asymmetric Cascade Reaction of Stable Sulfur Ylides with Nitroolefins: Scope,
Enantioselective [4+2] Cycloadditions of 2-Vinyl-1H-indoles with 3-Nitro-2H-chromenes Catalyzed by a
Chiral Squaramide Catalyzed Asymmetric Conjugate Additions of 3-Substituted Oxindoles to Vinylphosph
Enantioselective Synthesis of Highly Substituted Chromans by a Zinc(II)-Catalyzed Tandem Friedel-Cra
Visible-Light-Driven Photoredox Catalysis in the Construction of Carbocyclic and Heterocyclic Ring S
Synthesis of Indoles through Highly Efficient Cascade Reactions of Sulfur Ylides and N-(ortho-Chloro
Visible light induced intermolecular [2+2]-cycloaddition reactions of 3-ylideneoxindoles through ene
An organocatalytic Michael-aldol cascade: formal [3+2] annulation to construct enantioenriched spiro
Synthesis of Indolo[1,2-a]Quinoxalines via a Pd-Catallyzed Regioselective C-H Olefination/Cyclizatio
Enantioselective Cascade Reactions of Stable Sulfur Ylides and Nitroolefins through an Axial-to-Cent
Facile Synthesis of Enantioenriched C(gamma)-Tetrasubstituted alpha-Amino Acid Derivatives via an As
Catalytic Asymmetric Aza-Michael-Michael Addition Cascade: Enantioselective Synthesis of Polysubstit
Pyrrolidinyl-sulfamide derivatives as a new class of bifunctional organocatalysts for direct asymmet
Formal [4+1] cycloaddition of camphor-derived sulfonium salts with aldimines: enantioselective synth
Oxidative cross-esterification of dithiolanes with alcohols through a cross-dehydrogenative coupling
Enantioselective Intramolecular Crossed Rauhut-Currier Reactions through Cooperative Nucleophilic Ac
Copper-Catalyzed Enantioselective Inverse Electron-Demand Hetero- Diels–Alder Reactions of Diazadien
Desulfonylation of Tosyl Amides through Catalytic Photoredox Cleavage of N-S Bond Under Visible-Ligh
[4+3] Cycloaddition of in situ generated azoalkenes with C,N-cyclic azomethine imines: e？cient synth
Enantioselective Construction of Oxa- and Aza-Angular Triquinanes through Tandem [4+1]/[3+2] Cycload
Enantioselective Synthesis of Highly Substituted Chromans by a Zinc(II)-Catalyzed Tandem Friedel– Cr
Direct sp(3) C-H acroleination of N-aryl-tetrahydroisoquinolines by merging photoredox catalysis wit
De Novo Synthesis of gamma,gamma-Disubstituted Butyrolactones through a Visible Light Photocatalytic
Metal-Free, Room-Temperature, Radical Alkoxycarbonylation of Aryldiazonium Salts through Visible-Lig
Iron-Catalysed Decarboxylative (4+1) Cycloadditions by Exploiting the Unique Reactivity of Iron-stab
P,S Ligands for the Asymmetric Construction of Quaternary Stereocentres in Pd-Catalyzed Decarboxylat
[3 + 2] Cycloaddition/Oxidative Aromatization Sequence via Photoredox Catalysis: One-Pot Synthesis o
Redox-Neutral a-Allylation of Amines by Combining Palladium Catalysis and Visible-Light Photoredox C
Asymmetric trapping of zwitterionic intermediates by sulphur ylides in a palladium-catalysed decarbo
Decarboxylative Alkynylation and Carbonylative Alkynylation of Carboxylic Acids Enabled by Visible-L
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