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Bal-xSrxA12Si208体系环境障碍涂层材料在1000℃空气环境下的抗熔盐腐蚀性能研究
  • ISSN号:1005-023X
  • 期刊名称:《材料导报》
  • 时间:0
  • 分类:TB332[一般工业技术—材料科学与工程]
  • 作者机构:[1]西北工业大学超高温结构复合材料重点实验室,西安710072
  • 相关基金:国家自然科学基金(51032006)
中文摘要:

采用溶胶一凝胶法制备了3种不同钡锶物质的量比的Bal-xSrxA12Si208(BSAS)体系粉体材料,其钡、锶物质的量比分别为1:0、0.75:0.25、0:1。将烧结得到的BSAS块体材料表面喷涂(8.5±0.2)mg/cmz的Na2SO。后,置于1000℃空气环境中进行熔盐腐蚀实验,研究其抗熔盐腐蚀性能。根据样品质量随腐蚀时间的变化,结合X射线衍射(XRD)和扫描电镜形貌分析(SEM)等结果,揭示其抗熔盐腐蚀机理。结果表明,B0.75S0.25AS腐蚀100h后质量变化最小,XRD分析其成分未发生明显变化,说明B0.75S0.25在1000℃时的抗熔盐腐蚀性能优于其它物质的量比的BSAS材料。

英文摘要:

The Bal-xSrxA12Si208 (BSAS) powders with different molar ratio of barium to strontium were pre- pared by sol-gel method. The molar ratios of Ba to Sr were 1 : 0, 0. 75 : 0. 25, 0 : 1, respectively. Then the sintered BSAS bulk materials sintering with a concentration of (8. 51-0. 2) mg/cm2 NazSO4 on their surfaces were used in the corrosion test at 1000℃ in air. The weight change as a function of the corrosion time was recorded. The phases of the as-prepared and corroded samples were observed by X-ray diffraction (XRD). And the microstructures of the corroded samples were investigated by scanning electron microscopy (SEM). The results showed that the weight change of Ba0. 75 Sr0. 2s AS was minimum after 100 h corrosion. XRD results demonstrated that its composite was constant after corrosion. It indicated that the B.0.75 So. 25 AS had a better molten salt corrosion resistance than the others.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主编:
  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:3397