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中文摘要：
通过在室温下还原前驱体制备了Ag@AgCl催化剂，并利用X射线粉末衍射仪（XRD）和场发射扫描电子显微镜（FE-SEM）对产物进行表征．设计了新型光化学-微热量系统，用该系统获得了Ag@AgCl光催化降解甲基橙实时、在线的热力学和动力学瞬态信息．研究结果表明，该降解过程首先经历吸热再迅速进入放热阶段，最后曲线恒定于一个长的放热平台，计算得到ab，ac和ad段的热效应分别为-0．2609，2．5845和40．7289J，放热平台cd的平均速率为2．581mJ／s，并详细探讨了该过程的微观降解机制．
英文摘要：
Ag@ AgCl photocatalyst was prepared by reduction of AgCl precursor at room temperature, and characterised by X-ray powder diffraction（XRD） and field-emission scanning electron microscope（FE-SEM）. process went through an initial endothermic reaction and followed by an exothermic stage which finally kept a constant exothermic rate for at least 4 h. The heat effects of ab, ac, and ad stages were -0. 2609, 2. 5845 and 40. 7289 J, respectively. Meanwhile, the steady rate of exothermic platform, the stage of cd, is 2. 581 mJ/s. The microscopic mechanism of photodegradation was discussed in detail.
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