CdMoO4 nano-octahedra 在房间温度在 situ 被种由反向微乳液。从这个生长过程的精力进化用 microcalorimetry 被监视。microcalorimetric 热流动(MCHF ) 曲线为随后的水晶生长为起始的反应,和两倍不连续的发热的山峰显示出一座典型吸热的山峰。与互补描述技术结合了,形态学的进化和 CdMoO4 nano-octahedra 的尺寸与 MCHF 山峰被相关。基于在 298.15 点的 microcalorimetric 结果, K 提供了的计算评估 7.56 的常数 ?袴 吗??
CdMoO4 nano-octahedra were grown in situ at room temperature by reverse-microemulsion. Energy evolution from this growth process was monitored using microcalorimetry. The microcalorimetric heat flow (MCHF) curve showed a characteristic endo- thermic peak for the initial reaction, and double discontinuous exothermic peaks for the subsequent crystal growth. Combined with complementary characterization techniques, the evolution of morphology and size of the CdMoO4 nano-octahedra were cor- related with the MCHF peaks. Calculations based on the microcalorimetric results at 298.15 K provided rate constants of 7.56×10^-5 s^-1 for the reaction and nucleation process and 1.59×10^-5 s^-1 for the crystallization process.