像网的 ZnO nanostructures 成功地在各种各样的温度用钾硝酸盐线路被综合了简化常规准备方法。同样准备的产品的结构和形态学被 X 光检查粉末衍射(XRD ) 和地排放扫描电子显微镜学(FE-SEM ) 描绘。显示出的结果反应温度是一个重要参数,并且在 nano 结构和生长参数之间有反馈效果,与结合了在 situ 微热量测定,三个系统的反应率常数被发现是:2.43 愠晦 ' 虡 N 杮映捡潴獲漠 ? 桴 ? 牣灯眠瑡牥爠煥極敲敭瑮
Web-like ZnO nanostructures have been successfully synthesized using the potassium nitrate route at various temperatures to simplify conventional preparation methods. The structures and morphologies of the as-prepared products were characterized by X-ray powder diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). The results showed that the reaction temperature was an important parameter, and that there was a feedback effect between nano-structure and growth parameters, combined with in situ micro-calorimetry, the reaction rate constants of the three systems were found to have been: 2.43×10-6, 2.70×10-8 and 3.12×10-7s-1 respectively. Furthermore, based on the relationship governing the potential differences between nanoand bulk ZnO, thermodynamic functions of nano-ZnO such as standard molar entropy (Sm,ZnO(nano)), standard molar Gibbs free energy of formation (△rGm,ZnO(nano)), and standard molar enthalpy of formation (△rHm,ZnO(nano)) have been calculated by the electrochemical method.