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Standard molar enthalpy of formation of uniform CdMoO4 nano-octahedra
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O643.11[理学—物理化学;理学—化学] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]College of Chemistry & Ecological Engineering, Guangxi University for Nationalities, Nanning 530006, China, [2]Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Nanning 530006, China
  • 相关基金:supported by the National Natural Science Foundation of China (20963001,21273050); Guangxi Natural Science Foundation of China (0991001z,2011GXNSFB018021)
中文摘要:

像网的 ZnO nanostructures 成功地在各种各样的温度用钾硝酸盐线路被综合了简化常规准备方法。同样准备的产品的结构和形态学被 X 光检查粉末衍射(XRD ) 和地排放扫描电子显微镜学(FE-SEM ) 描绘。显示出的结果反应温度是一个重要参数,并且在 nano 结构和生长参数之间有反馈效果,与结合了在 situ 微热量测定,三个系统的反应率常数被发现是:2.43 愠晦 ' 虡 N 杮映捡潴獲漠 ? 桴 ? 牣灯眠瑡牥爠煥極敲敭瑮

英文摘要:

Web-like ZnO nanostructures have been successfully synthesized using the potassium nitrate route at various temperatures to simplify conventional preparation methods. The structures and morphologies of the as-prepared products were characterized by X-ray powder diffraction (XRD) and field-emission scanning electron microscopy (FE-SEM). The results showed that the reaction temperature was an important parameter, and that there was a feedback effect between nano-structure and growth parameters, combined with in situ micro-calorimetry, the reaction rate constants of the three systems were found to have been: 2.43×10-6, 2.70×10-8 and 3.12×10-7s-1 respectively. Furthermore, based on the relationship governing the potential differences between nanoand bulk ZnO, thermodynamic functions of nano-ZnO such as standard molar entropy (Sm,ZnO(nano)), standard molar Gibbs free energy of formation (△rGm,ZnO(nano)), and standard molar enthalpy of formation (△rHm,ZnO(nano)) have been calculated by the electrochemical method.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676