中文摘要：

合成了带甲氧基和羟基官能团的二茂铁膦配体,评价了它们在钯催化的Suzuki-Miyaura偶联反应中的性能,发现带甲氧基的膦配体对钯催化的Suzuki-Miyaura偶联反应有更好的性能,可催化富电子溴代芳烃和缺电子氯代芳烃与苯硼酸反应高产率地生成相应的联芳烃产物.

英文摘要：

Ferrocenyl phosphines with methoxy and hydroxy groups have been synthesized and evaluated as supporting ligands in the palladium-catalyzed Suzutd-Miyaura cross-coupling reaction. It was found that the phosphine having methoxy group as supporting lidand afforded better palladium catalyst with Pd（OAc）2, which can catalyze electron-rich aryl bromides and electron-deficient aryl chlorides to couple with phenylboronic acid to form the corresponding biaryls in high yields.