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中文摘要：
用哌嗪和丙胺作模板剂在水热条件下合成了微孔材料NH4[Ni（H2O）2Al2（PO4）3]；单晶解析表明该结构与以往的金属磷酸铝大有不同，结构中的镍原子是八配位的，且与铝的位置区别明显；单晶结构数据，元素分析，拉曼光谱表明NH4[Ni（H2O）2Al2（PO4）3]材料的八元环孔道中只含有NH，离子；热重分析和焙烧后的XRD图谱显示，该材料在350℃和空气条件下焙烧2h，仍然保持其原来的骨架结构；若焙烧温度为550℃，则结构被破坏．
英文摘要：
A Nickel-substituted aluminophosphate NH4 [Ni （H2O）2Al2 （PO4）3] has been synthesized hydrothermally in the presence of piperazine and propylamine as organic additaments. Single-crystal refinement showed that is different from most of the metal-substituted aluminophosptates, Ni in the structure is octahedral coordinated, and is distinguished from that of Al, which is trigonal-bipyramidal coordinated. The single crystal data, elemental analysis, and Raman spectroscopy confirmed that NH4 [Ni （H2O）2Al2 （PO4）3] contained only NH4^＋ cations in the 8-ring channels as compensating ions. Thermal analysis revealed that this material was thermally stable after heated at 350 ℃ for 2 h in air.
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