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螺旋碳纤维的顺磁响应
  • ISSN号:1005-023X
  • 期刊名称:材料导报
  • 时间:2012
  • 页码:17-19-
  • 分类:O473[理学—半导体物理;理学—物理]
  • 作者机构:[1]西南交通大学材料科学与工程学院,成都610031
  • 相关基金:国家自然科学基金(51173148;90305003);CAST航天科技创新基金(CAST20101004SWJTU01)
  • 相关项目:基于配位聚合的纳米螺旋纤维生长机理及螺旋纤维纸研制
作者: 周祚万|
中文摘要:

采用化学气相沉积法制备了螺旋碳纤维,通过XRD、EDX和SEM对样品进行了表征和分析,采用研磨方法考察了螺旋结构的破坏情况,并对比了研磨前后样品的低温磁性。结果表明,在有效去除催化剂的情况下,螺旋形貌被破坏以后,碳纤维的抗磁性信号增强。基于单电子受缚于螺旋线的物理模型对实验结果进行分析和讨论,认为螺旋形貌具有顺磁响应,并阐释了其产生机理。

英文摘要:

The helical carbon fibers were fabricated using chemical vapor deposition (CVD) process and were characterized by XRD, EDX and SEM. The magnetic properties of helical carbon fibers were studied experimentally. The response to external magnetic field was tested by SQUID at 3K. It showed that the magnetization of helical carbon fiber response negatively to external magnetic field, and the diamagnetism of the carbon fibers without helical structure was stronger than helical carbon fibers. The observation of experiments indicated that paramagnetism was caused by helical structure. In addition, the mechanism of the magnetic property of helical structure was qualitative studied by the model of a free electron constrained on a helical coil. The results showed paramagnetism induced by electronic bro- ken-chirality in mesoseale can be realized in a helical structure.

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期刊信息
  • 《材料导报:纳米与新材料专辑》
  • 主管单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主办单位:重庆西南信息有限公司(原科技部西南信息中心)
  • 主编:
  • 地址:重庆市渝北区洪湖西路18号
  • 邮编:401121
  • 邮箱:matreved@163.com
  • 电话:023-67398525
  • 国际标准刊号:ISSN:1005-023X
  • 国内统一刊号:ISSN:50-1078/TB
  • 邮发代号:
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:3397