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中文摘要：
在水热条件下（160℃），通过十二硅钨酸（H4[SiW12O40】-14H2O）、氯化铜（CuCl22H2O）和1,4-二（1H-1，2，4-三氮唑-亚甲基）苯反应，合成了结构新颖的多酸基配合物[Cu2（bbtz）4（SiW12O40）】（1）．X射线单晶衍射结果表明，该配合物中的金属一有机框架是一个具有六边形孔道的三维网状结构，而杂多阴离子[SiW12O40】4-作为四连接点以配位键连接到六边形孔道内，形成一个基于多酸的高维、高连接网络．
英文摘要：
A new polyoxometalate-based compound, [Cu2（bbtz）4（SiW12O40）] （1）, has been synthesized under hydrothermal conditions by reaction of H4[SiW12O40] 14H2O, CuC12.2H2O and 1,4-bis（1,2,4-triazol-l-ylmethyl）benzene. Single crystal X-ray diffraction shows that the metal-organic moieties in 1 form a highly connected 3D framework with hexagonal channels, while the [SiW12o40]4- polyanions act as four-connected linkages incorporated into the channels.
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