锂离子电池的电化学性能取决于电极材料,电解质以及隔膜。锂离子在这些材料中的传输途径和速率直接影响锂离子电池的电化学性能。最近为了提高锂离子电池的能量密度和输出功率,科学家们开展了一系列锂离子传输机理研究。本文综述了锂离子在不同电极材料、电解质、自组装膜中的传输扩散机理和其研究进展,并对各种机理进行了比较分析,指出了探索锂离子传输机理过程中遇到的瓶颈和今后的研究热点。
The electrochemical performances of Li ion battery depend on the electrode materials,electrolyte and septum.The transmission path and rate of Li ion in these materials directly affect the electrochemical performances of Li ion battery.Recently in order to improve the energy density and the output power of Li ion battery,a series of studies on the mechanism of lithium ion transport have been carried out.This paper reviewed the diffusion mechanisms of lithium ion in different electrode materials,electrolytes,self assembled membrane and its research progress.The various mechanisms were compared and evaluated.We also pointed out the bottleneck in the mechanism research of lithium ion transfer and hot issues in the futher research.