合成了新型水溶性显色剂标题化合物(DBNSESDAA)。在pH8.0的硼砂-盐酸缓冲介质中,Triton X-100存在下,该试剂与镉(Ⅱ)生成络合比为3:1的红色配合物。试剂有很好的灵敏度、选择性和水溶性。用双波长法测得表观摩尔吸光系数ε为2.1×10^5L·mol^-1·cm^-1,镉量在0~20μg/25mL范围内遵守比尔定律。用该试剂测定了电池厂废水和环境水中的痕量镉,结果满意。
A new water soluble reagent 2, 6-dibromo-4-nitrophenyl-4'-(β-ethyl sulfate) sulfonylbenzenediazoaminoazobenzene (DBNSESDAA) was synthesized. In the pre-sence of Triton X- 100, Cd (Ⅱ) reacted with DBNSESDAA to form a red complex with a molar ratio of 1 : 3 in a medium of borax-HCl buffer of pH 8.0. Its apparent molar absorptivity was 2.1×10^5 L·mol^-1·cm^-1 as determined by the dual-wavelength spectrophotometry. The Beer's law was obeyed in the concentration range of 0~20 μg/25 mL for Cd(Ⅱ). The reagent had good sensitivity, selectivity and water solubility. It had been used to determine Cd (Ⅱ) concentration in wastewater and environmental water of battery factory successfully.