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N-(末端三甲基硅苄基甘氨酸肽链)-2,3-萘二甲酰亚胺的光诱导单电子转移成环反应
  • ISSN号：0253-2786
  • 期刊名称：Chinese Journal of Organic Chemistry
  • 时间：2012
  • 页码：1290-1295
  • 分类：O621.25[理学—有机化学;理学—化学]
  • 作者机构：[1]哈尔滨师范大学化学化工学院,哈尔滨150025
  • 相关基金：国家自然科学基金（No.20972036）、国家自然科学基金（No.21171045）、黑龙江省自然科学基金（No.B200913）和黑龙江省高校科技创新团队建设计划项目（No.2011TD010）.
  • 相关项目：多功能复合孔生物活性玻璃的合成、组装及骨修复性能研究
作者： 岳群峰|曲凤玉|魏树权|谭广慧|
关键词： 光诱导, 单电子转移, 2, 3-萘二甲酰亚胺, 苄基甘氨酸肽链:环肽, photoinduced, single electron transfer, 2,3-naphthalimide, benzylglycine peptide chain, cyclopeptide
中文摘要：

以苄基甘氨酸为起始物合成了新型分子内给受电子体系Ⅳ_（末端三甲基硅苄基甘氨酸肽链）-2，3-萘酰亚胺（1）．1在MeOH-30％H20中发生光诱导单电子转移反应，以很高的区域选择性生成新型环苄基甘氨酸肽化合物2．所有新化合物均经MS和NMR确定结构．

英文摘要：

Benzylglycine was used as starting material for the synthesis of novel intramolecular electron donor-accepter sys- tem N-（amidosilane terminated polybenzylglycine peptide chain）-2,3-naphthalimide （1）. 1 could undergo a photoinduced sin- gle electron transfer cyclization reaction in MeOH-30% H20 solvent to provide novel cyclopolyglypeptides 2 in high regioselectivity. The structures of all the new compounds were characterized by MS and NMR techniques.

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多功能复合孔生物活性玻璃的合成、组装及骨修复性能研究
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期刊信息
  • 《有机化学》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:中国化学会 中国科学院上海有机化学研究所
  • 主编：陈庆云
  • 地址：上海市枫林路354号
  • 邮编：200032
  • 邮箱：bianji@mail.sioc.ac.cn
  • 电话：021-54925244
  • 国际标准刊号：ISSN：0253-2786
  • 国内统一刊号：ISSN：31-1321/O6
  • 邮发代号:4-285
  • 获奖情况:
  • 中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）,中国北大核心期刊（2000版）
  • 被引量:14408