采用冷等静压技术,在150MPa的压力下对磷酸钙骨水泥粉体进行等静压处理,然后使其在一定的条件下进行水化。采用扫描电镜(Scanning electron microscope,SEM)、红外光谱(Fourier transform infrared spectrome-try,FTIR)、X射线衍射(X-raydiffraction,XRD)和压汞仪等测试手段对其水化产物的结构和性能进行研究。结果表明,经过等静压处理,磷酸钙骨水泥粉体水qLg,境被改变,部分水化产物的晶体形貌由细小的短棒状变为六棱柱状,但主要物相仍为羟基磷灰石;水化固化体的孔隙率由未经等静压处理时的(46.32±2.70)%降到(24.75±1.15)%,抗压强度由(12.62±2.70)MPa提高到(43.05±2.08)MPa。
Calcium phosphate cement(CPC) hydrated in a special environment after compressively treated by cold isostatic pressing technology at 150MPa. The hydrated products are characterized by scanning electron microscope (SEM), Fourier transform infrared spectrometry (FTIR), X-ray diffraction (XRD) and compressive strength of the hydrated bodies is tested with a universal materials testing machine. The results indicate that, under the isostatic pressing, the hydration environment of the CPC power is changed. The crystal morphology of a part of the hydrated products changes from short-rod-like to hexagonal-prism-like, but the main phase present in the hydrated bodies is still poorly crystalline hydroxyapatite(HA). The porosity of the hydrated bodies reduces form (46. 32±2. 70)% without i- sostatic pressing to (24. 75±1.15)% after isostatic pressing at 150MPa and the compressive strength of the hydrated bodies increased about 3. 6 times from (12. 62±2.70)MPa to (43. 05±2. 08)MPa.