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胶束增强型聚电解质微胶囊的制备
  • 期刊名称:高等学校化学学报,28(5):974-977,2007. (SCI)
  • 时间:0
  • 分类:O647.3[理学—物理化学;理学—化学] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]浙江大学医学院附属口腔医院,杭州310006, [2]浙江大学高分子复合材料研究所,杭州310027
  • 相关基金:浙江省科技攻关计划项目(批准号:2006c33012)、浙江省自然科学基金(批准号:Y205183)、国家自然科学重点基金(批准号:50333020)和国家“九七三”计划项目(批准号:2005CB623902)资助.
  • 相关项目:仿生医用高分子材料的研究
中文摘要:

采用杂化碳酸钙微球作为模板,利用LbL技术,选择聚苯乙烯磺酸钠(PSS),烯丙基胺的盐酸盐(PAH)和二烯丙基二甲基胺盐酸盐(PADA)聚电解质,分别组装了PAH/PSS(弱/强)聚电解质胶囊和PADA/PSS(强/强)聚电解质微胶囊.除去模板后得到了球形良好、分散均匀的聚电解质微胶囊.研究结果表明,利用杂化碳酸钙微球作为聚电解质微胶囊的模板,得到的微胶囊的囊壁厚而致密,同时,由于组装采用的聚电解质的种类不同,囊壁的微观形貌有较大差异.

英文摘要:

Hybrid CaCO3 particles were used as templates to fabricate two kinds of "micelles enhanced" polyelectrolyte capsules with three different polyelectrolytes such as poly(allylamine hydrochloride) , poly(sodium styrenesulfonate), and poly( di-allyldimethylammonium chloride) via LbL technique. Both of (PAIl/ PSS)6 and (PADA/PSS)6 capsules had good spherical shape and good dispersion by CLSM. In contrast with conventional polyelectroly-te capsules, these novel micelles enhanced capsules had thick and compact capsule wall. Meanwhile, fine FESEM images showed that there was a significant difference in microstructure and topology between the two kinds of capsules made of different component polyelectrolytes.

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