通过物理、电化学手段,对Pt粒径分别为1.5nm、2.3nm和3.3nm的Pt/C催化剂的活性和稳定性进行了考察。经过500次电势扫描[O.6-1.2V(vs.NHE)]后,3种催化荆的电化学活性面积(ECA)分别衰减为初始值的15%、19%和25%;扫描电势为0.9V时,单位ECA的电流密度分别上升为初始值的1.84倍、1.40倍和1.34倍。
The oxygen reduction reaction activity and durability of Pt/C catalysts with Pt particle size of 1.5 nm,2.3 nm and 3.3 nm were studied by physical and dactrochemieal methods. After 500 cycles of potential scan[0.6 - 1.2 V( vs. NHE) ], the dectrochemical active area(ECA)of 3 kinds of catalyst was degraded to 15%, 19% and 25% of the initial value, respectively. The ECA specific current density increased to 1. 84 times, 1.40 times and 1. 34 times at the scan potential of 0.9 V.