用共沉淀方法制备出平均粒径在10nm左右的Fe3O4纳米粒子,然后在阳离子表面活性剂的引导下采用原位化学氧化聚合法,合成出聚吡咯-Fe3O4纳米复合材料.同时对此纳米复合材料的结构和性能进行了研究.结果表明Fe3O4纳米粒子和聚吡咯之间存在着一定的相互作用,从而有利于吡咯单体在Fe3O4纳米粒子的表面发生聚合反应,进而Fe3O4纳米粒子被聚吡咯所包覆.聚吡咯/Fe3O4纳米复合材料同时具有导电性和磁性,其导电性随着Fe3O4纳米粒子含量的增加先增大后减小,磁性则始终随着Fe3O4纳米粒子含量的增加而增大.
The Fe3O4 nanoparticles with about 10 nm average diameter were firstly prepared with codeposition method, then the polypyrrole (PPy)-Fe3O4 nanocomposites were synthesized in the suspen- sion solution of Fe3O4 nanoparticles via in situ chemical oxidative polymerization under the direction of cationic surfactant. Meanwhile, the structures and properties of the nanocomposites were studied. The results show that there are interactions between Fe3O4 nanoparticles and PPy, which makes that pyrrole monomer polymerize preferentially at the surfaces of the Fe3O4 nanoparticles so that the Fe3O4 nanoparticles are coated by PPy. The nanocomposites have both conductibility and magnetic performance. As the Fe3O4 content is gradually improved, the conductivity firstly enhances and then decreases, however, the saturation magnetization enhances all through.