2,5-piperazinedione 的新衍生物, 1,4-di (2-methoxyphenyl )-2,5-piperazinedione (I) ,被 N-2-methoxyphenyl chloroacetamide,和它的结构的 cyclocondensation 反应综合被元素的分析,红外, 1H NMR 和单身者描绘水晶 X 光检查衍射方法。水晶属于单斜晶的系统,有统一房间尺寸 a=0.56934 (10 ) nm 的空格组 P21/c, b=1.3880 (2 ) nm, c=1.00329 (17 ) nm, =90.376 (3 )? e
A new derivative of 2,5-piperazinedione, 1,4-di(2-methoxyphenyl)-2,5-piperazinedione (I), was synthesized by the cyclocondensation reaction of N-2-methoxyphenyl chloroacetamide, and its structure was characterized by elemental analysis, IR, ^1H NMR and single crystal X-ray diffraction method. The crystal belongs to monoclinic system, space group P21/c with unit cell dimensions a=0.56934(10) nm, b=1.3880(2) nm, c=1.00329(17) nm, β= 90.376(3)°, V= 0.7928(2) nm^3, Z=2, Dc = 1.367 g·cm^-3,μ = 0.98 cm^-1, R and wR being 0.0606 and 0.1564 respectively for 1549 unique reflections with 1247 observed reflections [I〉2σ(I)]. The molecule has a crystallographically imposed symmetry center. The three rings in the molecule are each coplanar with their attached groups, excluding methyl H atoms and the H atoms attached to the piperazinedione ring, while the whole molecule is not planar, with dihedral angles of 74.7(1)° between the piperazinedione and each of the two aromatic rings. The crystal structure is stabilized by van der Waals and dipole-dipole forces.