以硝基苯废水处理反应器内的污泥为菌源,采用间歇反应的方法分别考察Fe^3+,Ni^2+,Zn^2+,Al^3+,Cr(Ⅵ)和Cu^2+6种金属离子及盐度对硝基苯厌氧生物降解过程的影响。结果表明,适宜质量浓度的Fe^3+,Ni^2+,Zn^2+,Al^3+和Cr(Ⅵ)可促进硝基苯的降解。当ρ(Fe^3+)为5mg/L,ρ(Ni^2+),ρ(Zn^2+)和ρ(Al^3+)为1.0mg/L及ρ[Cr(Ⅵ)]为0.50mg/L时,硝基苯的降解速率提高5%~23%。当ρ(Fe^3+),ρ(Ni^2+),ρ(Zn^2+),ρ(Al^3+),ρ[Cr(Ⅵ)]和ρ(Cu^2+)分别大于50,10.0,5.0,5.0,5.0和0.25mg/L时,金属离子开始对硝基苯降解菌产生抑制作用,毒性顺序为Cu^2+〉Cr(Ⅵ)〉Al^3+〉Zn^2+〉Ni^3+〉Fe^3+。硝基苯降解菌生长的最佳盐度为0.25%-1.00%。
The effects of six metal ions including Fe^3+, Ni^2+, Zn^2+, Al^3+ , Cr(Ⅵ), Cu^2+, and salinity on anaerobic degradation of nitrobenzene were investigated in batch reactors. Nitrobenzene degradation bacteria were obtained from a reactor for nitrobenzene wastewater. The results showed that preferable mass concentrations of Fe^3+, Ni^2+, Zn^2+, Al^3+ and Cr(Ⅵ) had accelerated nitrobenzene degradation. When their mass concentrations were 5, 1.0, 1.0, 1.0 and 0.5 mg/L respectively, the nitrobenzene degradation rate increased by 5 %-23 % . However, nitrobenzene degradation bacteria were inhibited when their mass concentrations exceeded 50, 10.0, 5.0, 5.0, 5.0 and 0.25 mg/L respectively. Toxicity order in mass was Cu^2+〉 Cr(Ⅵ) 〉 Al^3+〉 Zn^2+〉 Ni^+2 〉 Fe^3+. Optimal salinity for nitrobenzene degradation bacteria was between 0.25% and 1.00%.