以丁基缩水甘油醚和苯酚为起始原料,进行开环缩合反应制得1-丁氧基-3-苯氧基丙-2-醇.再与羟基对甲苯磺酰氧基苯反应得到[4-(2-羟基-3-丁氧基-1-丙氧基)]二苯碘鎓-六氟锑酸盐(简称BPI·SbF6),产率达79%.用^1HNMR、UV、IR和元素分析对其结构进行了分析.初步研究了以BPI·SbF6为阳离子光引发剂的脂肪族环氧(CY179)感光体系的感光特性,结果表明CY179/BPI·SbF6感光体系有一定的后固化活性。
[4-(2-hydroxy-3-butoxy-1-propoxy)phenyl] phenyliodonium hexafluoroantimonate (BPI·SbF6) was prepared by the reaction of 2-propanol, 1-butoxy-3-phenoxy with [hydroxy(tosyloxy)iodo] benzene in approximately 79 % yield. The later product BPI·SbF6 was identified by infrared spectrum, UV spectrum, ^1HNMR spectrum and dement analysis. The characteristic curves of photopolymerization system CY179/BPI·SbF6 with different concentration of initiator BPI·SbF6 and the characteristic post-curves of photopolymerization system CY179/BPI·SbF6 with different UV curing time were studied.