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重金属螯合剂处理垃圾焚烧飞灰的稳定化技术
  • ISSN号:0438-1157
  • 期刊名称:《化工学报》
  • 时间:0
  • 分类:X524[环境科学与工程—环境工程]
  • 作者机构:[1]河海大学浅水湖泊综合治理与资源开发教育部重点实验室,江苏南京210098, [2]河海大学环境学院,江苏南京210098
  • 相关基金:国家自然科学基金项目(51079049)
中文摘要:

随着我国社会经济的发展、城市化进程的加快以及人们物质生活的提高,全国城市生活垃圾年产生量已达1.5亿吨以上,并以每年8%~10%的速率增加[1-3]。城市垃圾焚烧是我国垃圾处置的重要手段,在焚烧过程中将产生大量飞灰,飞灰产量与垃圾种类、焚烧条件、焚烧炉型及烟气处理工艺有关,一般约占被焚烧垃圾量的3%~5%。

英文摘要:

In view of treatment efficiency and stability about stabilization treatment of fly ash from municipal solid waste incineration,a stabilization technology was developed for treating heavy metals in fly ash using organic heavy metal chelator ammonium dipropyl dithiophosphate(ADD).The effect of pH on heavy metal leached amount from stabilized fly ash was studied.The contents of different forms of heavy metals in fly ash were compared before and after stabilization treatment with ADD chelator,and the stabilization effect was analyzed with different amounts of ADD chelator.The result showed that stabilization rate against Pb,Zn,and Cd of 1.5% ADD chelator reached 95.6%,85.5% and 93.4% respectively,and the amounts of Pb,Zn,and Cd in the leachate met the Pollution Control Standards for Hazardous Waste Landfill(GB 18598—2001)at pH values exceeding 3.The contents of Pb,Zn and Cd bound to carbonates in fly ash after ADD chelator treatment was significantly decreased with significantly increased contents bound to organic matter.The Pb,Zn and Cd stable form contents increased by 15.4%,17.1% and 24.3% respectively,and accordingly reduced the risk of secondary pollution of stabilized products under environment change.The stabilization effect of ADD chelator on heavy metals in fly ash was apparently better than that of inorganic stabilizing agent lime and sodium sulfide.

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期刊信息
  • 《化工学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国化工学会 化学工业出版社
  • 主编:李静海
  • 地址:北京市东城区青年湖南街13号
  • 邮编:100011
  • 邮箱:hgxb126@126.com
  • 电话:010-64519485
  • 国际标准刊号:ISSN:0438-1157
  • 国内统一刊号:ISSN:11-1946/TQ
  • 邮发代号:2-370
  • 获奖情况:
  • 中国科协优秀期刊二等奖,化工部科技进步二等奖,北京全优期刊奖,中国期刊方阵“双效”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:35185