目的研究红树林植物海榄雌Avicennia marina枝、叶的化学成分。方法采用硅胶柱色谱、葡聚糖凝胶SephadexLH-20柱色谱、HPLC等方法分离纯化,通过现代波谱技术鉴定其结构。结果从海榄雌枝、叶的提取物中分离获得10个化合物,鉴定结构分别为acteoside(Ⅰ)、isoacteoside(Ⅱ)、syringaresinol(Ⅲ)、5,7-二羟基-3’,4’,5’-三甲氧基黄酮(Ⅳ)、3吲哚甲酸(Ⅴ)、白桦酸(Ⅵ)、白桦醇(Ⅶ)、羽扇豆醇(Ⅷ)、白骨壤醌C(Ⅸ)和山柰酚(Ⅹ)。结论化合物Ⅰ~Ⅵ为首次从该植物中分离得到。
Objective To investigate the chemical constituents in the aerial parts of mangrove plant Avicennia marina. Methods The isolated compounds Ⅰ - Ⅹ were obtained by the combination of silica gel, Sephadex LH-20 column chromatographies and by semi-preparative HPLC separation. Structural elucidation was conducted by the modern spectral method. Results Ten compounds were isolated and identified from the aerial parts of A. marina, including acteoside ( Ⅰ ), isoacteoside ( Ⅱ ), syringaresinol ( Ⅲ ), 5, 7-dihydroxy-3', 4', 5'-trimethoxyflavone ( Ⅳ ), indolyl-3-carboxylic acid ( Ⅴ ), betulinic acid (Ⅵ ), betullin (Ⅶ), lupeol (Ⅷ), avicequinone C (Ⅸ), and kaempferol (Ⅹ). Conclusion Compounds Ⅰ -Ⅵ are isolated from A. marina for the first time.