位置:成果数据库 > 期刊 > 期刊详情页
Recent developments in homobimetallic reagents and catalysts for organic synthesis
  • ISSN号:1001-6538
  • 期刊名称:Chinese Science Bulletin
  • 时间:0
  • 页码:1753-1769
  • 分类:O643.36[理学—物理化学;理学—化学] TQ421[化学工程]
  • 作者机构:[1]Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
  • 相关基金:This work was supported by the National Natural Science Foundation of China (20972025) and the China National Petroleum Corporation ( CNPC) Innovation Foundation (2010D-5006-0504).
  • 相关项目:多取代的邻苯醌双亚胺类配体的合成及在乙烯的聚合、三聚、四聚等反应中的应用
中文摘要:

因为他们作为试剂并且作为催化剂在器官的合成起重要作用, Organometallics 是有用器官的化学药品的一个家庭。他们能根据他们包含的金属的数字被分类。二金属的混合物是重要 organometallics,他们是取决于二金属是否是一样的 homobimetallic 或 heterobimetallic 或不同。在这份报纸,我们集中于 homobimetallic 混合物。Homobimetallic 混合物通常被用作 dianions 在器官的合成与 electrophiles 反应。最近, homobimetallics 也在器官的反应例如被用作催化剂在不对称的反应。

英文摘要:

Organometallics are a family of useful organic chemicals because they play important roles in organic synthesis as reagents and as catalysts. They can be classified according to the number of metals they contain. Bimetallic compounds are important organometallics and they are either homobimetallic or heterobimetallic depending on whether the two metals are the same or different. In this paper, we focus on homobimetallic compounds. Homobimetallic compounds are generally used as dianions to react with electrophiles in organic synthesis. Recently, homobimetallics have also been used as catalysts in organic reactions such as in asymmetric reactions.

同期刊论文项目
同项目期刊论文