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低温固化热致变色涂层辐射特性
  • ISSN号:0023-074X
  • 期刊名称:《科学通报》
  • 时间:0
  • 分类:TQ633[化学工程—精细化工]
  • 作者机构:南京理工大学能源与动力工程学院,南京210094
  • 相关基金:国家自然科学基金(51406086,51225602); 江苏省自然科学基金(BK20140783); 南京理工大学2014“紫金之星”计划基金资助
中文摘要:

以溶胶凝胶法制备的高纯La1-xSrxMnO3(x=0.125,0.175,0.2)纳米粉末为填料,分别以热塑性丙烯酸树脂和松油醇@乙基纤维素为基料制备成涂层浆料,并涂覆于铝基底表面,再分别以低温120℃和180℃固化La1-xSrxMnO3热致变色涂层.实验表征了纳米粉末的物相,表面形貌,观察了涂层的微观形貌.并利用稳态卡计法测量了热致变色涂层在173-370 K温度范围内全半球发射率随温度的变化.研究结果表明:两种不同树脂为基料的涂层都表现出热致变色特性,其发射率增幅达0.45.由于低温固化涂层制备工艺简单,能够适用于复杂表面的涂覆应用,在航天热控中具有潜在的应用前景.

英文摘要:

Thermal control device based on thermochromis plays an important role in spacecrafts thermal management by automatically adjusting its radiative properities in response to large temperature gradients. The thermal management ability was determined by the device surface radiation performance. During the sun shadow, it is required to dissipate heat as little as possible from spacecraft, which is a low emittance device. While, it desired the device emittance is large enough to meet the heat dissipation requirement facing with the direct sunlight. As a type thermochromic material, La1-xSrxMnO3(LSMO) has obtained broad attention because it showed a considerable superiority in saving energy consumption in space thermal management. It can hold the heat at low temperature due to its low emittance behavior, whereas dissipate the excess heat at high temperature for its high emittance properties. In this work, we prepared the La1-xSrxMnO3(x=0125, 0.175, and 0.2) nanoparticles by sol-gel method from the precursors such as lanthanum nitrate hexahydrate, strontium nitrate and manganese nitrate solution(50%). LSMO nanoparticles were dispersed homogeneously in a solution of resins. The mixture then was spin-coated on the clean Al substrates. After standing for 10 h, the coating was cured at 120℃. The structure, morphology, and composition analysis of LSMO nanoparticles or coatings were investigated by X-ray diffraction technique, scanning electron microscopy, and the energy dispersive X-ray spectroscopy, respectively. The total hemispherical emittance of coating was measured by calortmetric method, which test sample was suspended in the center of a liquid nitrogen thermostat. According to the input power, sample temperature, and thermostat temperature, the emittance can be indirectly obtained. Two resins, which is the acrylic resin and the solution of terpineol and ethyl cellulose respectively, was considered to investigated the effect of reslin type on the emittance of coatings. The result of X-ray diffraction show

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期刊信息
  • 《科学通报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国科学院
  • 主编:周光召
  • 地址:北京东黄城根北街16号
  • 邮编:100717
  • 邮箱:csb@scichina.org
  • 电话:010-64036120 64012686
  • 国际标准刊号:ISSN:0023-074X
  • 国内统一刊号:ISSN:11-1784/N
  • 邮发代号:80-213
  • 获奖情况:
  • 首届国家期刊奖,中国期刊方阵“双高”期刊,第三届中国出版政府奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),美国数学评论(网络版),美国工程索引,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:81792