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稀土对挤压态Cu-7Ni-7Al-2Fe-2Mn合金耐蚀性能影响
  • ISSN号:1000-4343
  • 期刊名称:《中国稀土学报》
  • 时间:0
  • 分类:TG174.22[金属学及工艺—金属表面处理;金属学及工艺—金属学]
  • 作者机构:[1]河南科技大学材料科学与工程学院,河南洛阳471023, [2]河南省有色金属材料科学与加工技术重点实验室,河南洛阳471023, [3]有色金属共性技术河南省协同创新中心,河南洛阳471023, [4]中南大学材料科学与工程学院,湖南长沙410083, [5]北京有色金属研究总院有色金属材料制备加工国家重点实验室,北京100088
  • 相关基金:国家重点研发计划项目(2016YFB0301401); 国家基金委重点基金项目(U1502274); 河南省创新型科技团队项目(C20150014); 河南省高校科技创新团队支持计划项目(14IRTSTHN007)资助
中文摘要:

研究了稀土元素对Cu-7Ni-7Al-2Fe-2Mn合金耐海水浸泡腐蚀性能的影响。结果表明,合金以均匀腐蚀为主,当浸泡时间小于48 h时(12,24和48 h),合金腐蚀速率对稀土含量敏感度较高,24 h时稀土含量0.0000%,0.0146%和0.0352%的合金腐蚀速率分别为0.1720,0.1311和0.1065 g·m^-2·h^-1,随着稀土含量增加,敏感度降低,24 h时稀土含量0.0000%,0.0146%和0.0352%的合金腐蚀速率相差分别为0.1311,0.0328 g·m^-2·h^-1,分别降低42%和15%;经96和168 h浸泡后,稀土元素含量对合金腐蚀速率没有明显改善,腐蚀速率均在0.0300 g·m^-2·h^-1左右;合金腐蚀表面钝化膜质量随稀土元素含量增加而提高,48 h前稀土含量越高,钝化膜质量越高,48 h后稀土对钝化膜影响较小;随稀土添加合金电化学性能提高,稀土含量0.0352%时合金电荷转移电阻Rt最大,达到1.651×10^4Ω·cm^2,钝化膜对基体保护作用最好。

英文摘要:

This paper studied the influence of RE content on microstructure and corrosion resistance of extruded Cu-7Ni-7Al-2Fe-2Mn alloy. The results showed that the alloy was mainly uniform corrosion,when the soaking time was less than 48 h( 12,24 and 48 h),the rare earth content of the alloy corrosion sensitivity was higher. The corrosion rates were 0. 1720,0. 1311 and 0. 1065 g·m^-2·h^-1when the rare earth contents were 0. 0000%,0. 0146%and 0. 0352% respectively after soaked 24 h,with increase of the rare earth content and decrease of the sensitivity.The alloy corrosion rate differences were 0. 1311 and 0. 0328 g·m^-2·h^-1,that rare earth contents were 0. 0000%,0. 0146% and 0. 0352% respectively after soaked 24 h,it was reduced by 42% and 15%; the rare earth element content of the alloy had no significant improvement to all of the corrosion rates,alloy corrosion surface passivation film increased with the addition of rare earth elements. For the rare earth content the higher of the quality of the passivation film before 48 h,the smaller the impact of rare earth passivation film after 48 h. With the addition of rare earth,the electrochemical properties of the alloy was improved,the charge transfer resistance Rtmaximum reached 1. 651 × 10^4Ω·cm^2 when the rare earth content 0. 0352%,the protection performance of the passivation film was best.

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期刊信息
  • 《中国稀土学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国稀土学会
  • 主编:徐光宪
  • 地址:北京新街口外大街2号
  • 邮编:100088
  • 邮箱:jrechina@263.net
  • 电话:010-62014832
  • 国际标准刊号:ISSN:1000-4343
  • 国内统一刊号:ISSN:11-2365/TG
  • 邮发代号:2-612
  • 获奖情况:
  • 优秀科技期刊奖,中国科协择优资助期刊,中国科协期刊奖
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:12811