中文摘要：

设计并合成了两个五员瓜环（Q[5]）桥联K＋和Na＋形成的新型配合物[K（H2O）2Na（H2O）Q[5]]（ClO4）2·6H2O（1）,[KNaH（H2O）4Q[5]]n（ClO4）3n·3nH2O（2）.利用单晶X射线衍射进行结构测定,结果表明,配合物1中Q[5]起着一个双五齿配体的作用,每个端口的5个羰基氧原子分别和钾离子和钠离子配位,形成分子胶囊;配合物2中每个钾离子分别通过与相邻的2个Q[5]端口的相邻一对羰基氧原子配位,使得配合物形成一维链状结构,同时Q[5]还提供1个羰基氧原子与Na＋配位,氢键使得配合物形成三维超分子结构.

英文摘要：

Two new complexes based on cucurbit[51 uril and bridged K ＋ and Na ＋ [K（ H2O）2 Na（ H2O）Q[5] 1 （C1Q）2.6H2O （1）, [KNaH（H2O）4Q[5]],,（C104）3,,.3nH2O （2）, where Q[5] represents cucurbit[5]uril, have been synthesized and characterized by X-ray diffraction. The crystal structure shows that two portals of Q [ 5]were lidded by Na ＋ and K ＋ respectively in complex 1, where Q [5 ] acts as a bi-fivedentate ligand. In complex 2, K ＋ and Q [ 5] form columnar one-dimensional coordination polymers, in which Q [ 5 ] molecules stack atop one another through coordination of their two neighboring carbonyl groups to K ＋ in between. Q [ 5 ] also contribute one carbonyl oxygen to coordinate with Na＋. The complex assembled into a three-dimensional supramolecular structure through hydrogen bonds.