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一个本科生化学综合设计实验——双偶极Ru（Ⅱ）配合物和普鲁士蓝自组装多层膜的研究
  • ISSN号：0476-0301
  • 期刊名称：《北京师范大学学报：自然科学版》
  • 时间：0
  • 分类：O641.4[理学—物理化学;理学—化学] TP212.3[自动化与计算机技术—控制科学与工程;自动化与计算机技术—检测技术与自动化装置]
  • 作者机构：[1]北京师范大学化学学院,北京100875
  • 相关基金：国家自然科学基金资助项目（20771016,20971016,90922004）;北京市自然科学基金资助项目（2072011）;北京市大学生科学研究与创业计划基金资助项目;高等学校博士点专项科研基金资助项目（20060027002）;北京师范大学本科生科学研究基金和北京师范大学分析测试基金资助项目
作者： 孙伟海[1], 马淑风[1], 杨胜[1], 耿翀[1], 韩枫[1], 张红娟[1], 王科志[1]
关键词： 双核钌配合物, 普鲁士蓝, 自组装膜, 紫外一可见光谱, 循环伏安技术, ruthenium, Prussian blue, self-assembled films, UV-visible spectroscopy, cyclic voltammetry
中文摘要：

用一种双偶极Ru（II）配合物和普鲁士蓝分别代替一个本科生化学综合设计实验中的半菁和杂多阴离子，成功地制备了双偶极Ru（II）配合物和普鲁士蓝的静电自组装多层膜，并通过紫外一可见光谱和电化学技术对薄膜进行了表征．结果表明：多层膜可被均匀沉积厚达至少12层，膜中普鲁士蓝与Ru（II）配合物之间发生较强的电荷转移作用，具有良好的电化学活性．

英文摘要：

To carry out an undergraduate comprehensive experiment, a new self-assembled multiplayer film was prepared by alternating electrostatic adsorption of Prussian blue （PB） and a dipolar Ru（ II ） complex, and was characterized by UV-visible spectroscopy and cyclic voltammetry. An analysis of UV-vis spectroscopy revealed that the film was uniformly deposited up to 12 layers or more, and that the charge transfer between PB and the Ru （ II ） complex may occur in the film. Cyclic voltammetry showed that this novel inorganic-organic composite film is of good electrochemical activity, with two PB- and one Ru-based redox couples.

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期刊信息
  • 《北京师范大学学报：自然科学版》
  • 中国科技核心期刊
  • 主管单位:中华人民共和国教育部
  • 主办单位:北京师范大学
  • 主编：刘文彪
  • 地址：北京新外大街19号
  • 邮编：100875
  • 邮箱：JBNUNS@bnu.EDU.CN
  • 电话：
  • 国际标准刊号：ISSN：0476-0301
  • 国内统一刊号：ISSN：11-1991/N
  • 邮发代号:82-406
  • 获奖情况:
  • 1997年全国第二届科技期刊评比一等奖,1999年教育部优秀科技期刊二等奖,1999年首届国家期刊奖,中国期刊方阵“双高”期刊
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  • 被引量:10672