基于钌配合物染料的敏化太阳能电池与传统的硅半导体太阳能电池相比,具有较低的成本和较高的光电转换效率(8%~11%)。本文重点从钌配合物染料分子中固定配体的选择、辅助配体中引进具有空穴传输功能的三苯胺(或咔唑)基团以及配合物摩尔消光系数的提高3方面介绍近年钌配合物染料分子设计的研究进展。
This review highlights recent advances on the molecular engineering of ruthenium(Ⅱ) complex-based dyes, special attention has been paid on the topics of selection of anchoring ligands, ancillary ligands containing holetransport functional triphenylamine and carbazole groups, and enhancements in molar extinction coefficients.