以KCl为钾源、新疆某地所产斜发沸石为吸附剂,研究斜发沸石对K^+的动力吸附与解吸效果,并探讨吸附时间、K^+初始浓度与吸附量的关系。用PH=5的HCl溶液和(Ca^2+Mg^2+)浓度/(mmol·L^-1)为1.6,3.2,6.4,12.8,19.2,25.6的混合溶液对饱和吸附了K^+的斜发沸石进行解吸,实验结果表明:沸石对K^+的吸附在4min能达到最大吸附率的96%,30min内达到平衡。Langmuir吸附等温式能对吸附曲线进行很好的描述。单位质量沸石对K^+的最大吸附量为44.53×10^-3以阳离子交换吸附为主。pH-5的HCl溶液对K^+的解吸量最小,随解吸溶液中(Ca^2+Mg^2+)浓度增加,解吸滞后系数减小,解吸速率远小于吸附速率。解吸量的自然对数与解吸时间的自然对数呈现明显的线性关系,用指数方程对(Ca^2+Mg^2+)浓度为25.6mmol/L的解吸曲线进行拟合,R=0.998,拟舍方程为qt=3.890t^0.210。理论上将吸附的K^+全部解吸出来需要74.4d。
The clinoptilotite occurred in Xinjiang is taken as adsorbent to study the effect of adsorption/desorption of clinoptilotite on K+ and discuss the relation between amount of absorption and the absorption time as well as initial concentration of K^+. Clinoptilotite adsorbed saturated K^+ is desorbed by HCl solution(pH=5) and (Ca^2+ +Mg^2+) with concentration of 1.6,3.2,6.4, 12.8,19.2,25.6 mmol/L. It is showed that the absorption of clinoptilotite to K^+ reaches 96% at 4 minutes,getting balanced within 30 minutes, and the amount of maximum absorption is 44.53 )〈 10.3, dominant by cation absorption. When pH = 5, the amount of desorption of HCl to K^+ reaches its minimum. The hysteresis coefficients decreases as the concentration of (Ca^2+ +Mg^2+) increases, and the desorption rate is much lower than absorption rate. The natural logarithm of desorption quantity is linearly proportional to desorption time. The desorption curve with a (Ca^2+ + Mg^2+) concentration of 25.6 mmol/L is matched by exponent equation and obtain a fitting equation of q, = 3. 890t^0.210 with R = 0. 998. Theoretically, it takes 74. 4 days to desorb all adsorbed K^+.