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Effects of substrate characteristics on the passivation performance of ALD-Al2O3 thin film for high-efficiency solar cells
  • ISSN号:1674-4926
  • 期刊名称:《半导体学报:英文版》
  • 时间:0
  • 分类:TN304.21[电子电信—物理电子学] TM914.4[电气工程—电力电子与电力传动]
  • 作者机构:[1]School of Physics and Engineering, Institute for Solar Energy Systems, State Key Laboratory of Optoelectronic Materials andTechnologies, Sun Yat-Sen University, Guangzhou 510275, China
  • 相关基金:Project supported by the National Natural Science Foundation of China (No. 61176055) and the Science and Technology Project of Guangdong Province, China (No. 2011 A080804009).
中文摘要:

Atom layer deposition(ALD)-Al2O3 thin films are considered effective passivation layers for p-type silicon surfaces. A lower surface recombination rate was obtained through optimizing the deposition parameters. The effects of some of the basic substrate characteristics including material type, bulk resistivity and surface morphology on the passivation performance of ALD-Al2O3 are evaluated in this paper. Surface recombination velocities of 7.8 cm/s and 6.5 cm/s were obtained for p-type and n-type wafers without emitters, respectively. Substrates with bulk resistivity ranging from 1.5 to 4Ω·cm were all great for such passivation films, and a higher implied Voc of 660 mV on the 3Ω·cm substrate was achieved. A minority carrier lifetime(MCL) of nearly 10 μs higher was obtained for cells with apolished back surface compared to those with a textured surface,which indicates the necessity of the polishing process for high-efficiency solar cells. For n-type semi-finished solar cells, a lower effective front surface recombination velocity of 31.8 cm/s was acquired, implying the great potential of(ALD)-Al2O3 thin films for high-efficiency n-type solar cells.

英文摘要:

Atom layer deposition (ALD)-Al2O3 thin films are considered effective passivation layers for p-type silicon surfaces. A lower surface recombination rate was obtained through optimizing the deposition parameters. The effects of some of the basic substrate characteristics including material type, bulk resistivity and surface morphology on the passivation performance of ALD-Al2O3 are evaluated in this paper. Surface recombination velocities of 7.8 cm/s and 6.5 cm/s were obtained for p-type and n-type wafers without emitters, respectively. Substrates with bulk resistivity ranging from 1.5 to 4 Ω · cm were all great for such passivation films, and a higher implied Voc of 660 mV on the 3 Ω · cm substrate was achieved. A minority carrier lifetime (MCL) of nearly 10 μs higher was obtained for cells with a polished back surface compared to those with a textured surface, which indicates the necessity of the polishing process for high-efficiency solar cells. For n-type semi-finished solar cells, a lower effective front surface recombination velocity of 31.8 cm/s was acquired, implying the great potential of (ALD)-Al2O3 thin films for high-efficiency n-type solar cells.

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期刊信息
  • 《半导体学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国电子学会 中国科学院半导体研究所
  • 主编:李树深
  • 地址:北京912信箱
  • 邮编:100083
  • 邮箱:cjs@semi.ac.cn
  • 电话:010-82304277
  • 国际标准刊号:ISSN:1674-4926
  • 国内统一刊号:ISSN:11-5781/TN
  • 邮发代号:2-184
  • 获奖情况:
  • 90年获中科院优秀期刊二等奖,92年获国家科委、中共中央宣传部和国家新闻出版署...,97年国家科委、中共中央中宣传部和国家新出版署三等奖,中国期刊方阵“双效”期刊
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  • 被引量:7754