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Synthesis of Fluoroalkylated Allylic-β-hydroxyesters and Fluoroalkylated ,β,γ-Epoxy Esters from Ethyl 3-Hydroxy-4-pentenoate
  • ISSN号：1001-604X
  • 期刊名称：《中国化学：英文版》
  • 分类：TQ225.4[化学工程—有机化工] S379.5[农业科学—农产品加工;农业科学—农艺学]
  • 作者机构：[1]Laboratory for Advanced Material and Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China, [2]School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, China
  • 相关基金：project supported by the National Natural Science Foundation of China （NNSFC） （Nos. 20972050, 21172148）.
作者： 方向[1], 熊英[1], 王琼[1], 赵敏[1], 吴范宏[1,2]
关键词： 甲酸乙酯, 羟基酯, 环氧酯, 烯丙基, 合成, 碳酸钠水溶液, 脱卤化氢, 反应产物, ethyl 3-hydroxy-4-pentenoate, fluoroalkylated allylic-β-hydroxyesters, fluoroalkylated β,γ-epoxy esters
中文摘要：

fluoroalkylated 的顺序的转变使内收与氟化的碘化物从乙醇 3-hydroxy-4-pentenoate 获得了被报导。dehydrohalogenation 使内收被赞成面对 triethylamine 给 fluoroalkylated 不饱和的 -hydroxy 酉旨。并且 intramolecular SN2 反应产品， fluoroalkylated，环氧基树脂酉旨，在 10% 水的钠碳酸盐答案被获得。

英文摘要：

A sequential transformation of fluoroalkylated adducts obtained from ethyl 3-hydroxy-4-pentenoate with fluorinated iodides was reported. The dehydrohalogenation of adducts was favored to give fluoroalkylated unsaturated β-hydroxy esters in the presence of triethylamine. And intramolecular SN42 reaction products, fluoroalkylated β,γ-epoxy esters, were obtained in 10% aqueous sodium carbonate solution.

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期刊信息
  • 《中国化学：英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编：
  • 地址：上海市枫林路354号中科院上海有机化学研究所
  • 邮编：200032
  • 邮箱：
  • 电话：021-54925243
  • 国际标准刊号：ISSN：1001-604X
  • 国内统一刊号：ISSN：31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,荷兰文摘与引文数据库,美国科学引文索引（扩展库）,日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175