acridin-9-ylmethoxycarbonyl (Amoc ) 的合成和光化学被描述为为白酒的一个新光化学地可移动的保护组。白酒的三碳酸盐 13 通过 9-hydroxymethylacridine 的冷凝作用和白酒的 chloroformates 被综合包括本甲基酒精, phenethyl 白酒和白酒半乳糖衍生物。保护的白酒的光分解作用能高效地在 100200 的效率(Qu1 ) 释放相应白酒(量收益 Qu1=0.0110.023,和臼齿的吸收率 =9.1 吗?
Synthesis and photochemistry of acridin-9-ylmethoxycarbonyl (Amoc) as a new photochemically removable protecting group for alcohols were described. Three carbonates of alcohols 1-3 were synthesized through condensation of 9-hydroxymethylacridine and chloroformates of alcohols, including benzyl alcohol, phenethyl alcohol and one galactose derivative. The photolysis of protected alcohols can efficiently release the corresponding alcohol in the efficiencies (Qulε) of 100-200 (quantum yield Qul=0.011-0.023, and molar absorptivity ε= 9.1 × 10^3-9.8 × 10^3 mol^-1·L·cm^-1) under 360 nm light.