中文摘要：

采用简单的方法原位还原铜（Ⅱ）为铜（Ⅰ）,合成了二苯基硫脲铜（Ⅰ）配合物C32H38ClCuN6O2S2,通过IR和元素分析等手段对其进行表征,并用X射线单晶衍射确定了其晶体结构.该配合物晶体属单斜晶系,P21/c空间群,晶胞参数为a=0.957 4（5） nm,b=3.210 7（17） nm,c=1.222 8（7） nm; β=111.877（8）＆#176;,V=3.488（3） nm3,Z=4,Dc=1.336 mg/m3,F（000）=1 464,最终结构偏差因子R1=0.047 5,ωR2=0.130 7.基于多种分子间氢键的作用,分子在固相中堆积成三维超分子结构.同时研究了此配合物的光谱性质、热稳定性及电化学行为.

英文摘要：

A copper（ I ） complex with N, N＇-diphenyl thiourea [ C32 H38 CICuN602S2 ] was synthe- sized by a facile method of in situ reduction of copper（ 11 ） to copper（ I ）. The structure was charac- terized by elemental analysis, IR and X ray single-crystal diffraction. The crystal structure of the complex belongs to monoclinic system with space group P21/c. The cell parameters were as follows： a=0.9574（5） rim, b=3.2107（17） nm, c=1.222 8（7） nm; β=111.877（8）°, v=3.4s8 （3） nm3, Z = 4, Dc = 1. 336 mg/m3, F（000） = 1464, and the final structure deviation factor Rl = 0. 047 5, foR2 = 0. 130 7. Based on muhiplicate intermolecular hydrogen bonds, three-dimentional supramolecular structure in the complex was fabricated in solid phase. Additionally, the spectral property, thermal stability and electrochemical behavior of the complex were also studied in order to provide a valuable reference and a theoretical basis for further study of the structures and functional properties of this kind of metal-organic complexes.